CAS No.1923-70-2,Tetrabutylammonium perchlorate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	1923-70-2
Name:	Tetrabutylammonium perchlorate
Article Data:	22

Formula:	C₁₆H₃₆N^.ClO₄
Molecular Weight:	341.919
Synonyms:	Ammonium, tetrabutyl-, perchlorate;1-Butanaminium, N,N,N-tributyl-, perchlorate;Tetrabutyl ammonium perchlorate;Tetra-n-butylammonium perchlorate;
EINECS:	217-655-5
Density:	1.0387 (rough estimate)
Melting Point:	211-215 °C
Solubility:	acetonitrile: 0.1 g/mL, clear, colorless
Appearance:	white powder
Hazard Symbols:	O, Xi
Risk Codes:	5-8-36/37/38
Safety:	17-26-36-36/37/39
Transport Information:	UN 1479 5.1/PG 2
PSA:	74.27000
LogP:	5.21790

Synthetic route

: 1643-19-2
tetrabutylammomium bromide

: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
With trimethyl phosphite; perchloric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent);	95%
With perchloric acid
With perchloric acid
With perchloric acid

: 74436-10-5
(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2

: silver perchlorate

: cis-[Pd(pentafluorophenyl)2(THF)2]

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;	A 90% B n/a

...Expand

: N-n-Bu4{Au(C6Cl5)2}

: silver perchlorate

A: [{Au(C6Cl5)2}Ag]n

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.;	A 90% B n/a

...Expand

: NBu4[Ag(C6F5)2]

: {Ag(CH2P(C6H5)3)2}(1+)*ClO4(1-)={Ag(CH2P(C6H5)3)2}ClO4

A: {Ag(C6F5)(CH2P(C6H5)3)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In diethyl ether stirred at room temp. for 8 h; filtered off (N(C4H9)4)(ClO4), soln. concd., addn. of n-hexane, pptn.; elem. anal.;	A 85% B n/a

...Expand

: 86392-02-1
(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2

: silver perchlorate

: cis-[Pd(C6Cl5)2(thf)2]

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;	A 80% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: 1020072-44-9, 132018-77-0
[Ag(OClO3)(tetrahydrothiophene)]

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washeed with hexane, dried in vac.;	A 80% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: 137400-80-7
{Ag(tetrahydrothiophene)}ClO4

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washed with hexane, elem. anal.;	A 79% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(tetrahydrothiophene)}

: (C4H8S)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, washing with i-PrOH, elem. anal.;	A 78% B n/a

...Expand

: (NBu4)2{trans-PtCl2(C6Cl5)2}

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

A: N(C4H9)4(1+)*PtAgCl2(C6Cl5)2(P(C6H5)3)(1-) = (N(C4H9)4){PtAgCl2(C6Cl5)2(P(C6H5)3)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); evapn., treatment with cold MeOH (0°C), filtn., washing (MeOH); elem. anal.;	A 77% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{cis-Pt(C6F5)(C6Cl5)2(triphenylphosphine)}

: ((C6H5)3P)(C6Cl5)2(C6F5)PtAg(P(C6H5)3)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 77% B n/a

...Expand

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Specification

The Tetrabutylammonium perchlorate is an organic compound with the formula C₁₆H₃₆N^.ClO₄. The systematic name of this chemical is N,N,N-tributylbutan-1-aminium perchlorate. With the CAS registry number 1923-70-2, it is also named as Ammonium, tetrabutyl-, perchlorate. The product's categories are Ammonium Polyhalides, etc. (Quaternary); Oxidation; Quaternary Ammonium Compounds; Synthetic Organic Chemistry; Detergents A to ZSynthetic Reagents; Detergents; Perchlorates; Ammonium SaltsSynthetic Reagents; Greener Alternatives: Catalysis; Phase Transfer Catalysts; Ammonium SaltsAnalytical Reagents; Electrochemistry; Supporting Electrolytes for Electrochemistry. Besides, it should be stored in a closed cool and dry place.

Physical properties about Tetrabutylammonium perchlorate are: (1)ACD/LogP: -1.72; (2)ACD/LogD (pH 5.5): -1.72; (3)ACD/LogD (pH 7.4): -1.72; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.78; (7)ACD/KOC (pH 7.4): 2.78; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 12.

When you are using this chemical, please be cautious about it as the following:
It contacts with combustible material may cause fire. Please keep away from combustible material. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
(2)InChI: InChI=1/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(3)InChIKey: KBLZDCFTQSIIOH-REWHXWOFAG
(4)Std. InChI: InChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(5)Std. InChIKey: KBLZDCFTQSIIOH-UHFFFAOYSA-M