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| CAS No.: | 19597-69-4 |
|---|---|
| Name: | LITHIUM AZIDE |
| Article Data: | 22 |
| Molecular Structure: | |
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| Formula: | LiN3 |
| Molecular Weight: | 48.9611 |
| Synonyms: | Lithiumazide (6CI,7CI,8CI) |
| Density: | g/cm3 |
| Melting Point: | decomposes at 115–298℃ [CRC10] |
| Boiling Point: | °Cat760mmHg |
| Flash Point: | °C |
| Solubility: | g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05] |
| Hazard Symbols: |
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| Risk Codes: | 26/27/28-32 |
| Safety: | The moist or dry salt explodes when heated to 115-298°C. Forms very shock-sensitive explosive mixtures with alkyl nitrates or dimethylformamide above 200°C. Incompatible with CS2. When heated to decomposition it emits very toxic fumes of Li2O and NOx. See also AZIDES and LITHIUM COMPOUNDS. |
| PSA: | 49.75000 |
| LogP: | 0.21376 |
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Chemistry
Molecular Structure of Lithium azide (CAS NO. 19597-69-4):
EINECS: 243-177-1
IUPAC Name: Lithium azide
Molecular Formula: LiN3
Molecular Weight: 48.961100 g/mol
H-Bond Donor: 0
H-Bond Acceptor: 2
Canonical SMILES: [Li+].[N-]=[N+]=[N-]
InChI: InChI=1S/Li.N3/c;1-3-2/q+1;-1
InChIKey: GUWHRJQTTVADPB-UHFFFAOYSA-N
Density: 1.088 g/mL at 25 °C
Boiling Point: 103 °C
Safety Profile
Safety Information of Lithium azide (CAS NO. 19597-69-4):
Hazard Codes: T+ 
Risk Statements: 26/27/28-32
R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed
R32:Contact with acid liberates very toxic gas
Safety Statements: 23-36/37/39-45
S23:Do not breathe vapour
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3287 6.1/PG 2
HazardClass: 4.1
The moist or dry salt explodes when heated to 115-298°C. Forms very shock-sensitive explosive mixtures with alkyl nitrates or dimethylformamide above 200°C. Incompatible with CS2. When heated to decomposition it emits very toxic fumes of Li2O and NOx. See also AZIDES and LITHIUM COMPOUNDS.
Specification
Lithium azide with cas registry number of 19597-69-4 is clear colorless solution, also known as Lithium azide (Li(N3)) ; Lithium triazide .