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CAS No.: | 2146-97-6 |
---|---|
Name: | 1,3-Disilacyclobutane, 1,1,3,3-tetrachloro- |
Article Data: | 11 |
Molecular Structure: | |
Formula: | C2H4Cl4Si2 |
Molecular Weight: | 226.037 |
PSA: | 0.00000 |
LogP: | 2.91800 |
1,1,3,3-tetrakis(dimethylamino)-1,3-disilacyclobutane
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
With Dichlorophenylphosphine In pentane | 100% |
5,6-Bis(trifluormethyl)-2,2-dichlor-2-silabicyclo<2.2.2>octa-5,7-dien
A
1,2-bis(trifluoromethyl)benzene
B
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
at 650℃; under 0.2 Torr; Product distribution; | A 79% B 36% |
Conditions | Yield |
---|---|
at 715℃; | 43% |
at 750℃; | 11% |
at 700℃; | |
at 850℃; high vacuum; |
1,1-dimethylsilacyclobutane
1,1-dichlorosilacyclobutane
A
1,1,3,3-tetramethyl-1,3-disiletane
B
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
at 690℃; | A n/a B n/a C 40% |
(1R,4S)-2,2-Dichloro-5,6-bis-trifluoromethyl-2-sila-bicyclo[2.2.2]octa-5,7-diene
A
1,2-bis(trifluoromethyl)benzene
B
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
at 650℃; under 0.2 Torr; |
1,1-dichlorosilacyclobutane
A
Methyltrichlorosilane
B
ethene
C
n-propyltrichlorosilane
D
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
at 570℃; for 0.00333333h; Further byproducts given. Title compound not separated from byproducts; |
1,1-dichlorosilacyclobutane
A
Methyltrichlorosilane
B
ethene
C
n-propyltrichlorosilane
D
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
at 570℃; for 0.00333333h; Product distribution; pulsed pyrolytic chromatography; thermal decomposition of 1,1-dichloro-1-silacyclobutane in inert atmosphere and in the presence of butadiene, role of intemediates; |
1,1-dichlorosilacyclobutane
A
Methyltrichlorosilane
B
methane
C
ethene
D
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
With sulphur hexafluoride In gas at 700 - 800℃; for 0.166667h; Mechanism; Irradiation; |
1,1,3,3-tetrachloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
With silver(II) fluoride | 90% |
dimethyl amine
1,1,3,3-tetrachloro-1,3-disilacyclobutane
1,3-bis(dimethylamino)-1,3-dichloro-1,3-disilacyclobutane
Conditions | Yield |
---|---|
Ambient temperature; | 76% |