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CAS No.: | 2370-18-5 | ||||||
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Name: | Galvinoxyl | ||||||
Article Data: | 16 | ||||||
Molecular Structure: | |||||||
Formula: | C29H41 O2 | ||||||
Molecular Weight: | 421.63 | ||||||
Synonyms: | p-Tolyloxy,2,6-di-tert-butyl-a-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)- (6CI,7CI,8CI);2,6-Di-tert-butyl-a-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxy;Coppinger's radical;Galvinoxy;Galvinoxyl Galvinoxyl;Galvinoxyl free radical;Galvinoxylradical;Phenoxy,4-[[3,5-bis(1,1-dimethylethyl)-4-oxo-2,5-cyclohexadien-1-ylidene]methyl]-2,6-bis(1,1-dimethylethyl)-; | ||||||
EINECS: | 219-133-2 | ||||||
Density: | 1.012g/cm3 | ||||||
Melting Point: |
158-159 °C(lit.) |
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Boiling Point: | 512.6°Cat760mmHg | ||||||
Flash Point: | 216.9°C | ||||||
Safety: |
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PSA: | 17.07000 | ||||||
LogP: | 8.33650 |
1-Chloro-4-iodobenzene
2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxyl
3-oxobenzo[d]isothiazole-2(3H)-carbaldehyde 1,1-dioxide
phenylboronic acid
Conditions | Yield |
---|---|
With potassium phosphate; sodium carbonate; N-ethyl-N,N-diisopropylamine at 120℃; for 24h; Mechanism; | 58% |
2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxyl
2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxy-benzylidene)-cyclohexa-2,5-dienone
Conditions | Yield |
---|---|
With N-phenylsalicylaldimine In ethyl acetate at 25℃; Kinetics; Reagent/catalyst; Solvent; |
2,6-di-tert-butyl-α-(3,5-di-tert-butyl-4-oxo-2,5-cyclohexadien-1-ylidene)-p-tolyloxyl
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
Conditions | Yield |
---|---|
With tetrabutylammonium tetrafluoroborate; N-ethyl-N,N-diisopropylamine In tetrahydrofuran; acetonitrile at 20℃; for 3h; Inert atmosphere; Schlenk technique; Glovebox; Electrochemical reaction; |