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| CAS No.: | 29091-21-2 |
|---|---|
| Name: | Prodiamine |
| Article Data: | 8 |
| Molecular Structure: | |
|
|
|
| Formula: | C13H17 F3 N4 O4 |
| Molecular Weight: | 350.298 |
| Synonyms: | Toluene-2,4-diamine,a,a,a-trifluoro-3,5-dinitro-N4,N4-dipropyl- (8CI); Barricade; Barricade(herbicide); Endurance; Endurance (herbicide); Factor; Kusablock;N3,N3-Dipropyl-2,4-dinitro-6-trifluoromethyl-1,3-phenylenediamine; Prodiamine |
| EINECS: | 249-421-3 |
| Density: | 1.384 g/cm3 |
| Melting Point: | 124-125° |
| Boiling Point: | 433 °C at 760 mmHg |
| Flash Point: | 215.7 °C |
| Solubility: | 0.013ppm at 25ºC in water |
| Appearance: | 48 |
| Hazard Symbols: | F;Xn;N |
| Risk Codes: | R11;R38;R50/53;R65;R67 |
| Safety: | Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of F− and NOx. |
| Transport Information: | UN 1145 |
| PSA: | 120.90000 |
| LogP: | 5.35800 |
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| Conditions | Yield |
|---|---|
| (i) EtOH, (ii) NH3; Multistep reaction; |
- 29091-20-1
N,n-dipropyl-3-chloro-2,6-dinitro-4-trifluoromethylaniline
- 29091-21-2
prodiamine
| Conditions | Yield |
|---|---|
| With ammonia In 1,4-dioxane at 95 - 100℃; for 40h; Sealed flask; | 0.345 g |
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Chemistry
Chemistry informtion about Prodiamine (CAS NO.29091-21-2) is:
IUPAC Name: Pentyl nitrite
Synonyms: 2,4-Dinitro-N',N'-Dipropyl-6-(Trifluoromethyl)Benzene-1,3-Diamine ; 2,4-Dinitro-N3,N3-Dipropyl-6-(Trifluoromethyl)-1,3-Benzenediamine ; Barricade ; Kusablock ; Prodiamine ; 1,3-Diamino-N(Sup1),N(Sup1)-Dipropyl-2,6-Dinitro-4-(Trifluoromethyl)Benzene ; 1,3-Diamino-N1,N1-Dipropyl-2,6-Dinitro-4-Trifluoromethylbenzene ; 2,4-Dinitro-N(Sup3),N(Sup3)-Dipropyl-6-(Trifluoromethyl)-M-Phenylenediamin
Product Categories: Protective Apparel Fabric ; PhenylenediamineAlphabetic ; Alpha sort ; DinitroanilinePesticides&Metabolites ; Herbicides ; N-PPesticides&Metabolites ; P ; Pesticides&Metabolites ; PON - PT
MF: C13H17F3N4O4
MW: 350.29
EINECS: 249-421-3
Density: 1.384 g/cm3
Flash Point: 215.7 °C
Boiling Point: 433 °C at 760 mmHg
Vapour Pressure: 1.06E-07 mmHg at 25°C
Enthalpy of Vaporization: 68.89 kJ/mol
Storage temp.: 0-6°C
Following is the molecular structure of Prodiamine (CAS NO.29091-21-2) is:
Uses
Prodiamine (CAS NO.29091-21-2) can be used as Dinitrophenyl amine herbicides.Application to 0.375-1.5kgAl/ha, it can effectively Control in alfalfa, cotton, ornamental crops, soybeans and other broad-leaved crops Tanaka to annual and perennial grass weeds, monocotyledonous and broad-leaved weeds.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | oral | > 15gm/kg (15000mg/kg) | Pesticide Manual. Vol. 9, Pg. 704, 1991. | |
| rat | LC50 | inhalation | 256mg/m3 (256mg/m3) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 19, Pg. S141, 1994. | |
| rat | LD50 | oral | 15380mg/kg (15380mg/kg) | "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 48, 1977. | |
| rat | LD50 | skin | > 2gm/kg (2000mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C249, 1991. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of F− and NOx.
Hazard Codes:
F
Xn
N
Risk Statements:
R11:Highly flammable.
R38:Irritating to skin.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65:Harmful: may cause lung damage if swallowed.
R67:Vapours may cause drowsiness and dizziness.
Safety Statements:
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: UN 1145
Specification
Prodiamine (CAS NO.29091-21-2) is a yellow crystals.