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Basic Information
CAS No.: 29091-21-2
Name: Prodiamine
Article Data: 8
Molecular Structure:
Molecular Structure of 29091-21-2 (Prodiamine)
Formula: C13H17 F3 N4 O4
Molecular Weight: 350.298
Synonyms: Toluene-2,4-diamine,a,a,a-trifluoro-3,5-dinitro-N4,N4-dipropyl- (8CI); Barricade; Barricade(herbicide); Endurance; Endurance (herbicide); Factor; Kusablock;N3,N3-Dipropyl-2,4-dinitro-6-trifluoromethyl-1,3-phenylenediamine; Prodiamine
EINECS: 249-421-3
Density: 1.384 g/cm3
Melting Point: 124-125°
Boiling Point: 433 °C at 760 mmHg
Flash Point: 215.7 °C
Solubility: 0.013ppm at 25ºC in water
Appearance: 48
Hazard Symbols: F;Xn;N
Risk Codes: R11;R38;R50/53;R65;R67   
Safety: Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of F and NOx.
Transport Information: UN 1145
PSA: 120.90000
LogP: 5.35800
Synthetic route
29091-09-6

2,4-dichloro-3,5-dinitro-benzotrifluoride

142-84-7

di-n-propylamine

29091-21-2

prodiamine

Conditions
ConditionsYield
(i) EtOH, (ii) NH3; Multistep reaction;
29091-20-1

N,n-dipropyl-3-chloro-2,6-dinitro-4-trifluoromethylaniline

29091-21-2

prodiamine

Conditions
ConditionsYield
With ammonia In 1,4-dioxane at 95 - 100℃; for 40h; Sealed flask;0.345 g
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Chemistry

Chemistry informtion about Prodiamine (CAS NO.29091-21-2) is:
IUPAC Name: Pentyl nitrite
Synonyms: 2,4-Dinitro-N',N'-Dipropyl-6-(Trifluoromethyl)Benzene-1,3-Diamine ; 2,4-Dinitro-N3,N3-Dipropyl-6-(Trifluoromethyl)-1,3-Benzenediamine ; Barricade ; Kusablock ; Prodiamine ; 1,3-Diamino-N(Sup1),N(Sup1)-Dipropyl-2,6-Dinitro-4-(Trifluoromethyl)Benzene ; 1,3-Diamino-N1,N1-Dipropyl-2,6-Dinitro-4-Trifluoromethylbenzene ; 2,4-Dinitro-N(Sup3),N(Sup3)-Dipropyl-6-(Trifluoromethyl)-M-Phenylenediamin
Product Categories: Protective Apparel Fabric ; PhenylenediamineAlphabetic ; Alpha sort ; DinitroanilinePesticides&Metabolites ; Herbicides ; N-PPesticides&Metabolites ; P ; Pesticides&Metabolites ; PON - PT
MF: C13H17F3N4O4
MW: 350.29
EINECS: 249-421-3 
Density: 1.384 g/cm3
Flash Point: 215.7 °C
Boiling Point: 433 °C at 760 mmHg
Vapour Pressure: 1.06E-07 mmHg at 25°C
Enthalpy of Vaporization: 68.89 kJ/mol
Storage temp.: 0-6°C
Following is the molecular structure of Prodiamine (CAS NO.29091-21-2) is:

Uses

Prodiamine (CAS NO.29091-21-2) can be used as Dinitrophenyl amine herbicides.Application to 0.375-1.5kgAl/ha, it can effectively Control in alfalfa, cotton, ornamental crops, soybeans and other broad-leaved crops Tanaka to annual and perennial grass weeds, monocotyledonous and broad-leaved weeds.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral > 15gm/kg (15000mg/kg)   Pesticide Manual. Vol. 9, Pg. 704, 1991.
rat LC50 inhalation 256mg/m3 (256mg/m3)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 19, Pg. S141, 1994.
rat LD50 oral 15380mg/kg (15380mg/kg)   "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 48, 1977.
rat LD50 skin > 2gm/kg (2000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C249, 1991.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Mildly toxic by ingestion. When heated to decomposition it emits very toxic fumes of F and NOx.
Hazard Codes:
FlammableF
HarmfulXn
DangerousN
Risk Statements:
R11:Highly flammable. 
R38:Irritating to skin. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R65:Harmful: may cause lung damage if swallowed. 
R67:Vapours may cause drowsiness and dizziness.
Safety Statements:
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
RIDADR: UN 1145

Specification

Prodiamine (CAS NO.29091-21-2) is a yellow crystals.