Detail of > 30018-16-7
- CAS Number:
- 30018-16-7
- Name:
Phosphonium,(2-ethoxy-1-methyl-2-oxoethyl)triphenyl-, bromide (1:1)
- Superlist Name:
- [1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide
- Formula:
- C23H24BrO2P
- Molecular Structure:
- Synonyms:
- (1-Carboxyethyl)triphenylphosphoniumbromide, ethyl ester (6CI,7CI);Phosphonium, (1-carboxyethyl)triphenyl-,bromide, ethyl ester (8CI);Phosphonium,(2-ethoxy-1-methyl-2-oxoethyl)triphenyl-, bromide (9CI);(2-Ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium bromide;
- Molecular Weight:
- 443.31
- EINECS:
- 250-002-2
- Melting Point:
- 152 °C
- Solubility:
- souble in water
- Appearance:
- White to off-white powder
- Hazard Symbols:
Xn, 
Xi- Risk Codes:
- 36/37/38-29-22
- Safety:
- 26-36-8-37/39Details
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Reference
- Polyprenyl compounds
- Polyprenyl compounds.There are some reagents like 30018-16-7 is used in this study. (Eisai Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho JP 59163375 A2 14 Sep 1984 Showa, 5 pp.Some commonly used reagents like 30018-16-7 is used in this experiment. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07D295-18. ICA: A61K031-535. APPLICATION: JP 83-36567 8 Mar 1983. DOCUMENT TYPE: Patent CA Section: 30 (Terpenes and Terpenoids) Polyprenyl compds. I [R = HO2CCMe:CH (II), HOCH2CMe:CH] were prepd. from I (R = Me2C:CH) (III). Thus, III was brominated with N-bromosuccinimide, the resulting bromide treated with K2CO3 in MeOH, the resulting epoxide (I, R = 3,3-dimethyl-2-oxiranyl) oxidized with HIO4, the resulting aldehyde (I, R = CHO) condensed with EtO2CCHMePPh3Br in CH2Cl2 contg. NaH, and the resulting I (R = EtO2CCMe:CH) hydrolyzed to give II, which was also obtained by fermn. of III with Nocardia species BPM1613. ..
- Polyprenyl compounds
- Polyprenyl compounds.There are some reagents like 30018-16-7 is used in this study. (Eisai Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho JP 59163375 A2 14 Sep 1984 Showa, 5 pp.Some commonly used reagents like 30018-16-7 is used in this experiment. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07D295-18. ICA: A61K031-535. APPLICATION: JP 83-36567 8 Mar 1983. DOCUMENT TYPE: Patent CA Section: 30 (Terpenes and Terpenoids) Polyprenyl compds. I [R = HO2CCMe:CH (II), HOCH2CMe:CH] were prepd. from I (R = Me2C:CH) (III). Thus, III was brominated with N-bromosuccinimide, the resulting bromide treated with K2CO3 in MeOH, the resulting epoxide (I, R = 3,3-dimethyl-2-oxiranyl) oxidized with HIO4, the resulting aldehyde (I, R = CHO) condensed with EtO2CCHMePPh3Br in CH2Cl2 contg. NaH, and the resulting I (R = EtO2CCMe:CH) hydrolyzed to give II, which was also obtained by fermn. of III with Nocardia species BPM1613. ..
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