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| CAS No.: | 359-41-1 |
|---|---|
| Name: | 1,1,1-Trifluoro-2,3-epoxypropane |
| Article Data: | 10 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H3F3O |
| Molecular Weight: | 112.051 |
| Synonyms: | Oxirane,(trifluoromethyl)- (9CI);Propane, 2,3-epoxy-1,1,1-trifluoro- (6CI,7CI,8CI);1,2-Epoxy-3,3,3-trifluoropropane;2-Trifluoromethyloxirane;3,3,3-Trifluoro-1,2-epoxypropane;3,3,3-Trifluoropropene epoxide;3,3,3-Trifluoropropene oxide;3,3,3-Trifluoropropylene oxide;Trifluoromethyloxirane; |
| EINECS: | -0 |
| Density: | 1.448 g/cm3 |
| Melting Point: | -80 |
| Boiling Point: | 33.5 °C at 760 mmHg |
| Flash Point: | -40°C |
| Solubility: | Not miscible with water. |
| Appearance: | colorless liquid |
| Hazard Symbols: |
 F,  T
|
| Risk Codes: | 11-20/21/22-36/37/38 |
| Safety: | 16-26-36 |
| Transport Information: | UN 1993 |
| PSA: | 12.53000 |
| LogP: | 0.94750 |
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| Conditions | Yield |
|---|---|
| With calcium hydroxide In water at 38 - 40℃; for 1h; Concentration; Reagent/catalyst; | 80.3% |
| With calcium hydroxide In water at 90℃; for 1h; | 74% |
| With sodium hydroxide at 85℃; | 70.2% |
- 311-86-4
2-bromo-1,1,1-trifluoropropan-3-ol
A
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
B
- 1514-82-5
2-bromo-3,3,3-trifluoropropene
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 0 - 95℃; |
- 137429-44-8
3-bromo-1,1,1-trifluoropropan-2-ol
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
| Conditions | Yield |
|---|---|
| With sodium hydroxide at 100℃; | 88% |
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
| Conditions | Yield |
|---|---|
| With sodium hydroxide |
- 383-68-6
3-acetoxy-2-bromo-1,1,1-trifluoropropane
A
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
B
- 1514-82-5
2-bromo-3,3,3-trifluoropropene
| Conditions | Yield |
|---|---|
| With sodium hydroxide In water at 100℃; Title compound not separated from byproducts.; |
| Conditions | Yield |
|---|---|
| Stage #1: 1,1,1-trifluoropropylene With N-Bromosuccinimide; sulfuric acid; acetic acid at 65 - 70℃; for 11h; Stage #2: With sodium hydroxide In water at 120 - 130℃; | 17.3 g |
| With dinitrogen monoxide at 20 - 300℃; under 750.075 Torr; for 4h; Kinetics; Reagent/catalyst; Inert atmosphere; |
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
| Conditions | Yield |
|---|---|
| With sodium hydroxide |
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
| Conditions | Yield |
|---|---|
| With sodium hydroxide |
- 677-21-4
1,1,1-trifluoropropylene
A
- 359-41-1
1,1,1-trifluoro-2,3-epoxypropane
B
- 460-40-2
3,3,3-trifluoropropanal
| Conditions | Yield |
|---|---|
| With dinitrogen monoxide at 20 - 300℃; under 750.075 Torr; for 4h; Kinetics; Reagent/catalyst; Inert atmosphere; |
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Chemistry
Molecular Structure:
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Molecular Formula: C3H3F3O
Molecular Weight: 112.0505
IUPAC Name: 2-(Trifluoromethyl)oxirane
Synonyms of Oxirane, (trifluoromethyl)- (CAS NO.359-41-1): 3,3,3-Trifluoropropane epoxide
CAS NO: 359-41-1
Classification Code: Fluorochemicals
Index of Refraction: 1.326
Molar Refractivity: 15.61 cm3
Molar Volume: 77.3 cm3
Surface Tension: 19.4 dyne/cm
Density: 1.448 g/cm3
Flash Point: °C
Enthalpy of Vaporization: 26.72 kJ/mol
Boiling Point: 33.5 °C at 760 mmHg
Vapour Pressure: 560 mmHg at 25°C
Safety Profile
Hazard Codes of Oxirane, (trifluoromethyl)- (CAS NO.359-41-1): 
F,
T
Risk Statements: 11-20/21/22-36/37/38
R11:Highly flammable.
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 16-26-36
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
RIDADR: 1993
Hazard Note: Flammable/Toxic/Keep Cold
HazardClass: 3
PackingGroup: II