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Detail of "459-56-3"

  • MSDS Download
  • CAS Number:
  • 459-56-3
  • Name:
  • Benzenemethanol,4-fluoro-

  • Superlist Name:
  • 4-Fluorobenzyl alcohol
  • Molecular Structure:
  • Formula:
  • C7H7FO
  • Molecular Weight:
  • 126.13
  • Synonyms:
  • Benzylalcohol, p-fluoro- (6CI,7CI,8CI);(4-Fluorophenyl)methanol;4-Fluorobenzenemethanol;p-Fluorophenylmethanol;NSC 63347;p-Fluorobenzyl alcohol;
  • EINECS:
  • 207-292-0
  • Density:
  • 1.173 g/cm3
  • Melting Point:
  • 23 °C
  • Boiling Point:
  • 202 °C at 760 mmHg
  • Flash Point:
  • 94.6 °C
  • Appearance:
  • colorless or slightly yellow liquid
  • Hazard Symbols:
  • IrritantXi,CorrosiveC
  • Risk Codes:
  • 14-34-36/37
  • Safety:
  • 23-24/25-45-36/37/39-27-26 Details

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CAS No.459-56-3 4-Fluorobenzyl alcoholCompetitive Product

4-Fluorobenzyl alcohol

Supplier:Hangzhou Share Chemical Co., Ltd [ China (Mainland)]

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CAS No.459-56-3 4-Fluorobenzyl alcohol

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CAS No.459-56-3 4-Fluorobenzyl alcohol

Assay:99.5%  Appearance:powder  Package:25kg/Cardboa...Storage:1-10MT

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CAS No.459-56-3 4-Fluorobenzyl alcohol

Assay:99%

Product Name:4-Fluorobenzyl alcohol Alias:P-FLUOROBENZYL ALCOHOL;(4-Fluorophenyl)methanol; (4-Fluoro-phenyl)-methano;4-Fluoro-benzenemethanol;Benzenemethanol, 4-fluoro- Molecular Formula:C7H7FO Molecular Weight:126.13 EINECS :207-292-0

Supplier:hangzhou fanting i/e chemical co,.ltd. [ China (Mainland)]

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CAS No.459-56-3 4-Fluorobenzyl alcohol

  Appearance:Colorless or...

Chemical Name: 4-Fluorobenzyl alcohol Synonyms: p-Fluorobenzyl alcohol Molecular Formula:C7H7FO Molecular Weight: 142.12 Boiling point: 181.2°C(82°C/3.466kpa) Flash point: 60°C Density:1.207 non-dangerous goods

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4-Fluorobenzylalcohol

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4-Fluoro?Benzyl?Alcohol

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4-FLUOROBENZYL ALCOHOL

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4-FLUOROBENZYL ALCOHOL

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CAS No.459-56-3 4-Fluorobenzyl alcohol

more details? Please contact us

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CAS No.459-56-3 4-Fluorobenzyl alcohol

6-FLUOROBENZYL ALCOHOL

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CAS No.459-56-3 4-Fluorobenzyl alcohol

6-FLUOROBENZYL ALCOHOL

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6-FLUOROBENZYL ALCOHOL

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CAS No.459-56-3 4-Fluorobenzyl alcohol

4-FLUOROBENZYL ALCOHOL

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Reference

Second Generation Fluorous DEAD Reagents Have Expanded Scope in the Mitsunobu Reaction and Retain Convenient Separation Features
Second Generation Fluorous DEAD Reagents Have Expanded Scope in the Mitsunobu Reaction and Retain Convenient Separation Features. Dandapani, Sivaraman; Curran, Dennis P. (Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, USA). Journal of Organic Chemistry, 69(25), 8751-8757 (English) 2004 American Chemical Society. CODEN: JOCEAH. ISSN: 0022-3263. DOCUMENT TYPE: Journal CA Section: 23 (Aliphatic Compounds) A first generation fluorous analog of di-Et azodicarboxylate (DEAD) [F3C(CF2)5CH2CH2O2CN:NCO2CH2CH2(CF2)5CF3, F-DEAD-1] gives lower yields of products than diisopropyl azodicarboxylate (DIAD) in Mitsunobu reactions involving hindered alcs. or less acidic pronucleophiles such as phenols. A variety of fluoroalkyl hydrazinedicarboxylates are prepd. 624-95-3 and 459-56-3 which are cas registry numbers are also used here. and their retention times on fluorous resin-based HPLC are detd.; two of the tested hydrazinecarboxylates are converted to the corresponding azodicarboxylate reagents, F-DEAD-2 [C8F17(CH2)3O2CN:NCO2CMe3] and F-DEAD-3 [C6F13(CH2)3O2CN:NCO2(CH2)3C6F13]. Mitsunobu reactions using either F-DEAD-2 and F-DEAD-3 and the fluorinated triphenylphosphine 4-Ph2PC6H4CH2CH2(CF2)7CF3 (F-TPP) are effective for a variety of alcs. and nucleophiles such as phenols, sulfonamides, and carboxylic acids; the yields of the corresponding Mitsunobu reactions using DIAD and triphenylphosphine give products in comparable or higher yields. Fluorous coproducts formed in reactions with F-DEAD-2 and F-TPP can be sepd. easily by fluorous chromatog., while Mitsunobu reactions using F-DEAD-3 and F-TPP as reagents can be sepd. by fluorous solid phase extn. .
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