Detail of "54512-75-3"

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CAS Number:
54512-75-3
Name:
1-Bromo-5-chloropentane
Molecular Structure:
Formula:
C₅H₁₀BrCl
Molecular Weight:
185.50 .
Synonyms:
Pentane, 1-bromo-5-chloro-;1-bromo-5-chloro-pentan;(1-Bromo-5-Chloropentane);
EINECS:
259-193-7
Density:
1.367 g/cm³
Boiling Point:
211 °C at 760 mmHg
Flash Point:
95 °C
Solubility:
insoluble in water
Appearance:
clear colourless liquid
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
23-24/25-37/39-26 Details
Transport Information:
UN 2810

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Reference

Cis-Alkenyl chlorides: Cis-Alkenyl chlorides. (Shin-Etsu Chemical Industry Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho JP 58177924 A2 18 Oct 1983 Showa, 5 pp. (Japanese). (Japan). CODEN: JKXXAF. CLASS: IC: C07C021-04; B01J027-10; C07C017-26. APPLICATION: JP 82-60692 12 Apr 1982. DOCUMENT TYPE: Patent CA Section: 23 (Aliphatic Compounds) Section cross-reference(s): 5 cis-RCH:CHCH2CH2(CH2)nCl (I, R = C1-8 alkyl; n = 4-8) were prepd. by Grignard reaction of cis-RCH:CHCH2CH2Cl (II) with Br(CH2)nCl in the presence of LiCuCl2 and/or Li2CuCl4 in THF. I were effective insect pheromones (no data). 16725-53-4 and 54512-75-3 are just another two chemicals used in this study. Thus, a Grignard reagent from 1 mol II (R = Et) was added to 1 mol Br(CH2)6Cl and Li2CuCl4 (from 410 mg LiCl and 676 mg CuCl2) in THF at 10-15°, and stirred at 40° to give 85% I (R = Et, n = 6), which (172 g) was treated with HOAc to give cis-9-dodecenyl acetate. .

Detail of "54512-75-3"

1-Bromo-5-chloropentane

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