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Detail of "59280-70-5"

  • CAS Number:
  • 59280-70-5
  • Name:
  • Acetamide,N-(4-chloro-2-fluorophenyl)-

  • Molecular Structure:
  • Formula:
  • C8H7ClFNO
  • Molecular Weight:
  • 187.6008
  • Synonyms:
  • 4-Chloro-2-fluoroacetanilide;4'-Chloro-2'-fluoroacetanilide;N-(4-Chloro-2-fluorophenyl)acetamide;N-(4-chloro-2-fluorophenyl)acetamide;p-Chlorofluoroacetanilide;
  • Density:
  • 1.352 g/cm3
  • Melting Point:
  • 154-156 °C(lit.)
  • Boiling Point:
  • 312.8 °C at 760 mmHg
  • Flash Point:
  • 143 °C
  • Appearance:
  • pink to light brown crystalline powder
  • Hazard Symbols:
  • ToxicT; IrritantXi
  • Risk Codes:
  • 23/24/25
  • Safety:
  • 45-36/37/39 Details

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Reference

Herbicidal isobenzofuranones
Herbicidal isobenzofuranones. Mumford, Franklin E. (du Pont de Nemours, E. I., and Co., USA). U.S. US 3990880 9 Nov 1976, 7 pp. (English). (United States of America). CODEN: USXXAM. CLASS: IC: C07D307-87. NCL: 071088000. APPLICATION: US 75-629550 6 Nov 1975. DOCUMENT TYPE: Patent CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 5 Cyclocondensation of 0.6 parts 2-[(4-chloro-2-fluorophenyl)carbamoyl]-1-cyclohexene-1-carboxylic acid (I) in dioxane in presence of dicyclohexylcarbodiimide 1 hr at room temp. gives 0.27 part II, an effective post- and preemergent herbicide. 2-FC6H4NHAc is chlorinated to give 2,4-FClC6H3NHAc which is hydrolyzed to 2,4-FClC6H3NH2 (III). 59280-70-5 is just another one chemical used in this study. Reaction of III with 1-cyclohexene-1,2-dicarboxylic anhydride gives I. .
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