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Basic Information
CAS No.: 639-47-4
Name: Morphinan-3-ol,7,8-didehydro-4,5-epoxy-6-methoxy-17-methyl-, (5a,6a)-
Article Data: 3
Molecular Structure:
Molecular Structure of 639-47-4 (Morphinan-3-ol,7,8-didehydro-4,5-epoxy-6-methoxy-17-methyl-, (5a,6a)-)
Formula: C18H21 N O3
Molecular Weight: 299.37
Synonyms: Heterocodeine;Morphine 6-methyl ether; NSC 134601; O6-Methylmorphine
Density: 1.34g/cm3
Boiling Point: 448.9°Cat760mmHg
Flash Point: 225.3°C
PSA: 41.93000
LogP: 1.79010
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Synthetic route
57-27-2

MORPHIN

74-88-4

methyl iodide

639-47-4

morphine 6-Methyl Ether

Conditions
ConditionsYield
Stage #1: MORPHIN With potassium hydride In tetrahydrofuran at 20℃; for 16.5h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran for 4.25h; Inert atmosphere;		25%
With potassium hydride In tetrahydrofuran for 6h; Ambient temperature;
57093-46-6

3-acetoxy-4,5α-epoxy-6α-methoxy-17-methyl-morphin-7-ene

639-47-4

morphine 6-Methyl Ether

Conditions
ConditionsYield
With sodium hydroxide In methanol for 8h; Heating;
639-47-4

morphine 6-Methyl Ether

oripavine-N-oxide hydrochloride

Conditions
ConditionsYield
Stage #1: morphine 6-Methyl Ether With 3-chloro-benzenecarboperoxoic acid In chloroform; isopropyl alcohol at -5℃; for 0.416667h;
Stage #2: With hydrogenchloride In chloroform; water; isopropyl alcohol		100%
639-47-4

morphine 6-Methyl Ether

21988-87-4

1,3,5-tris(bromomethyl)-2,4,6-trimethylbenzene

C66H75N3O9

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide In dichloromethane; water at 20℃; for 6h; Inert atmosphere;13%
639-47-4

morphine 6-Methyl Ether

108-24-7

acetic anhydride

57093-46-6

3-acetoxy-4,5α-epoxy-6α-methoxy-17-methyl-morphin-7-ene

Conditions
ConditionsYield
With pyridine for 2.5h; Ambient temperature;
639-47-4

morphine 6-Methyl Ether

57093-47-7

3-acetyloripavine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Py / 2.5 h / Ambient temperature
2: MnO2 / tetrahydrofuran
View Scheme
639-47-4

morphine 6-Methyl Ether

467-04-9

oripavine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: Py / 2.5 h / Ambient temperature
2: MnO2 / tetrahydrofuran
3: aq. NaOH / methanol
View Scheme
639-47-4

morphine 6-Methyl Ether

A

heterocodeine 3-acetate

heterocodeine 3-acetate

B

Morphine 3-Acetate 6-Methyl Ether

Conditions
ConditionsYield
With BaO; acetic anhydride In pyridine; waterA 1.08 g (97%)
B n/a
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    Morphinan-3-ol,7,8-didehydro-4,5-epoxy-6-methoxy-17-methyl-, (5a,6a)-Appearance:detailed see specifications Storage:Store in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/Pharmaceutical intermediat

    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

  • Nanjing Raymon Biotech Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-025-52181296

    Address:Block B, No. 918, Shuanglong Avenue

       Inquiry Now

  • 639-47-4

  • Casno:

    639-47-4

    639-47-4

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    High Cost-Effective Application:intermediates

    We are Hebei minshang biotechnology co. LTD., mainly deal in pharmaceutical intermediates and various chemicals. We are manufacturers and have our own factory. Products & Usage Ph

  • Hebei Minshang Biotechnology Co., Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:18032092709

    Address:hebei

       Inquiry Now

  • Morphinan-3-ol,7,8-didehydro-4,5-epoxy-6-methoxy-17-methyl-, (5a,6a)-

  • Casno:

    639-47-4

    Morphinan-3-ol,7,8-didehydro-4,5-epoxy-6-methoxy-17-methyl-, (5a,6a)-

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Morphinan-3-ol,7,8-didehydro-4,5-epoxy-6-methoxy-17-methyl-, (5a,6a)-Appearance:ask Storage:Keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:by air or by sea

    Shanghai PengMo Biotechnology Co., Ltd. is engaging in researching, developing, manufacturing and exporting advanced pharmaceutical intermediates and other fine chemicals. Our comp

  • Shanghai PengMo Biotechnology Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-13052359378

    Address:No.218 Hai Qu Road.Shanghai.China

       Inquiry Now

  • 639-47-4

  • Casno:

    639-47-4

    639-47-4

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Supply top quality products with a reasonable price Application:api

    Hebei Ruishun Trade Co.,Ltd registered capital one million, we have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center, we do

  • Hebei Ruishun Trade Co.,Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-311-68037669

    Address:WanDa commerce building ,yuhua district

       Inquiry Now

  • Total:35 Page 1 of 1 1
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