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Basic Information
CAS No.: 7450-69-3
Name: PHENYLPHOSPHORODIAMIDATE
Article Data: 11
Molecular Structure:
Molecular Structure of 7450-69-3 (PHENYLPHOSPHORODIAMIDATE)
Formula: C6H9 N2 O2 P
Molecular Weight: 172.123
Synonyms: Phenylphosphorodiamidate (6CI,7CI); Diamidophosphoric acid phenyl ester; Phenyldiamidophosphate; Phenyl phosphate diamide; Phosphoric acid phenyl esterdiamide
Density: 1.34g/cm3
Melting Point: 183-185 °C
Boiling Point: 313.8ºC at 760 mmHg
Flash Point: 143.6ºC
Solubility: 5.6g/L at 20℃
Appearance: white to grey powder and flakes
Risk Codes: R25; R36/37/38
Safety: 608629
PSA: 88.15000
LogP: 2.49150
Synthetic route
770-12-7

O-phenyl phosphorodichloridate

7450-69-3

phenyl diamidophosphate

Conditions
ConditionsYield
With ammonium hydroxide at -10℃; for 2.5h;90%
With ammonia In water at 5 - 20℃;88%
With ammonia In dichloromethane for 0.166667h;17.4%
108-95-2

phenol

A

2015-56-7

diphenylphosphoroamidate

B

7450-69-3

phenyl diamidophosphate

Conditions
ConditionsYield
With pyridine; chloroform; trichlorophosphate at -2℃; Eintragen des Reaktionsgemisches in fluessiges NH3;
7450-69-3

phenyl diamidophosphate

1310-73-2

sodium hydroxide

sodium phosphorodiamidate pentahydrate

Conditions
ConditionsYield
In sodium hydroxide boiling phenyl ester for 5 min in 4 M NaOH; cooling, addn. of EtOH, pptn., recrystn. (H2O-EtOH), drying (air, room temp.); elem. anal.;80%
7450-69-3

phenyl diamidophosphate

1663-67-8

malonoyl dichloride

64402-71-7

2-Phenyloxy-4,6-dioxo-hexahydro-1,3,2-diazphosphorin-2-oxid

Conditions
ConditionsYield
In diethyl ether 1.) R.T., 3 h, 2.) reflux, 1 h;17%
50-00-0

formaldehyd

7450-69-3

phenyl diamidophosphate

61578-57-2

C7H11N2O3P

Conditions
ConditionsYield
With sodium hydroxide In isopropyl alcohol
16513-17-0

methyltrimethylsilylamine

7450-69-3

phenyl diamidophosphate

18081-61-3

N,N'-Bis-trimethylsilyl-diamidophosphorsaeure-phenylester

Conditions
ConditionsYield
In diethyl ether
7450-69-3

phenyl diamidophosphate

999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

18081-61-3

N,N'-Bis-trimethylsilyl-diamidophosphorsaeure-phenylester

67-56-1

methanol

7450-69-3

phenyl diamidophosphate

A

22457-53-0

Diamidophosphorsaeuremethylester

B

108-95-2

phenol

Conditions
ConditionsYield
With water; manganese(ll) chloride at 25℃; methanolysis, also without H2O;
7450-69-3

phenyl diamidophosphate

108-95-2

phenol

Conditions
ConditionsYield
In water at 30℃; libratation from carboxymethylcellulose and hydrolysis;
7450-69-3

phenyl diamidophosphate

alkali

alkali

A

108-95-2

phenol

B

phosphoric acid diamide

phosphoric acid diamide

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