CAS No.7501-02-2,2-(2-BIPHENYLYLOXY)ETHANOL Suppliers

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Basic Information

Molecular Structure:
CAS No.:	7501-02-2
Name:	2-(2-BIPHENYLYLOXY)ETHANOL
Article Data:	5

Formula:	C₁₄H₁₄O₂
Molecular Weight:	214.264
Synonyms:	2-(2-phenylphenoxy)ethanol;beta-Hydroxyethyl ether of o-phenylphenol;Ethanol, 2- ([1,1-biphenyl]-2-yloxy)-;.beta.-Hydroxyethyl ether of o-phenylphenol;4-06-00-04581 (Beilstein Handbook Reference);Ethyl alcohol, 2-(o-biphenylyloxy)-;Ethanol, 2-((1,1-biphenyl)-2-yloxy)- (9CI);Ethanol,2-([1,1'-biphenyl]-2-yloxy)-;Ethyl alcohol, 2-(o-phenyl)phenoxy-;Ethanol, 2-(2-biphenylyloxy)-;
EINECS:	231-355-1
Density:	1.111 g/cm³
Boiling Point:	344.6 °C at 760 mmHg
Flash Point:	151.4 °C
PSA:	29.46000
LogP:	2.72470

Synthetic route

: 96-49-1
[1,3]-dioxolan-2-one

: 90-43-7
2-Phenylphenol

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

Conditions

Conditions	Yield
With potassium carbonate at 160℃; for 1h; Temperature; Reagent/catalyst;	99.2%

: 107352-46-5
ethyl (<1,1'-biphenyl>-2-yloxy)acetate

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 1h;	95%
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 1h;

: 90-43-7
2-Phenylphenol

: 107-07-3
2-chloro-ethanol

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

Conditions

Conditions	Yield
With potassium hydroxide

: 90-43-7
2-Phenylphenol

2-chloro-6-fluorobenzylhalide: 2-chloro-6-fluorobenzylhalide

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: K2CO3 / dimethylformamide / 4 h 2: LiAlH4 / tetrahydrofuran / 1 h / 0 °C View Scheme

: 90-43-7
2-Phenylphenol

diphenyl ether , 4-oxy-diphenyl: diphenyl ether , 4-oxy-diphenyl

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) NaH / 1.) DMF, 0 deg C, 2.) DMF, RT, overnight 2: 95 percent / lithium aluminium hydride / tetrahydrofuran / 1 h / 0 °C View Scheme

: 486-25-9
9-fluorenone

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

: 9,9-bis(3-phenyl-4-(2-hydroxyethoxy)phenyl)fluorene

Conditions

Conditions	Yield
With methanesulfonic acid; 3-mercaptopropionic acid In toluene at 50 - 80℃; for 5.5h; Time; Reagent/catalyst; Inert atmosphere;	90%
With 3-mercaptopropionic acid In 5,5-dimethyl-1,3-cyclohexadiene at 60℃; for 6h; Solvent;	87%
With sulfuric acid; 3-mercaptopropionic acid In 5,5-dimethyl-1,3-cyclohexadiene at 60 - 95℃; for 64h;

: 3240-94-6
N-(2-chlorethyl)morpholine

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

: 4-[2-(2-biphenyl-2-yloxy-ethoxy)-ethyl]-morpholine

Conditions

Conditions	Yield
With sodium; xylene

: 107-93-7
(E)-but-2-enoic acid

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

: trans-crotonic acid-[2-(biphenylyl-(2)-oxy)-ethyl ester]

Conditions

Conditions	Yield
With benzenesulfonic acid; benzene at 90 - 120℃;

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

: 119-67-5
o-carboxybenzaldehyde

: 102706-07-0
3-(2-biphenyl-2-yloxy-ethoxy)-phthalide

: 7501-02-2
2-(<1,1'-biphenyl>2-yloxy)ethanol

: 124-63-0
methanesulfonyl chloride

: 2-(<1,1'-biphenyl>-2-yloxy)ethanol methanesulfonate

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran for 1h; Ambient temperature;

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Specification

The Ethanol, 2-(o-biphenylyloxy)-, with the CAS registry number 7501-02-2, is also known as Ethanol, 2-((1,1'-biphenyl)-2-yloxy)- (9CI). Its EINECS registry number is 231-355-1. This chemical's molecular formula is C₁₄H₁₄O₂ and molecular weight is 214.26. Its IUPAC name is called 2-(2-phenylphenoxy)ethanol. The product should be sealed and stored in cool, dry place.

Physical properties of Ethanol, 2-(o-biphenylyloxy)-: (1)ACD/LogP: 2.67; (2)ACD/LogD (pH 5.5): 2.67; (3)ACD/LogD (pH 7.4): 2.67; (4)ACD/BCF (pH 5.5): 62.59; (5)ACD/BCF (pH 7.4): 62.59; (6)ACD/KOC (pH 5.5): 672.26; (7)ACD/KOC (pH 7.4): 672.26; (8)#H bond acceptors: 2; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 5; (11)Index of Refraction: 1.575; (12)Molar Refractivity: 63.69 cm³; (13)Molar Volume: 192.7 cm³; (14)Surface Tension: 43 dyne/cm; (15)Density: 1.111 g/cm³; (16)Flash Point: 151.4 °C; (17)Enthalpy of Vaporization: 62.12 kJ/mol; (18)Boiling Point: 344.6 °C at 760 mmHg; (19)Vapour Pressure: 2.47E-05 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: C1=CC=C(C=C1)C2=CC=CC=C2OCCO
(2)InChI: InChI=1S/C14H14O2/c15-10-11-16-14-9-5-4-8-13(14)12-6-2-1-3-7-12/h1-9,15H,10-11H2
(3)InChIKey: NOZAKUWNUGNDLI-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	75mg/kg (75mg/kg)		National Technical Information Service. Vol. AD691-490,