Detail of "7719-12-2"

Reference

Synthesis and structure of the first 10-P-3 species

Synthesis and structure of the first 10-P-3 species. Culley, Scott Anthony; Arduengo, Anthony J., III (Dep. Chem., Univ.Some commonly used reagents like 7719-12-2 and 88686-46-8 are used in this experiment. Illinois, Urbana, IL 61801, USA). J. Am. Chem. Soc., 106(4), 1164-5 (English) 1984. CODEN: JACSAT. ISSN: 0002-7863. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 75 The title 10-P-3 species I (ADPO; one of 3 resonance forms shown) was prepd. by cyclizing (Me3CCOCH2)2NH with PCl3 and its crystal structure detd. .

Infrared chemiluminescence in the reactions of 0

Infrared chemiluminescence in the reactions of 0.45 eV hydrogen atoms with molecular chlorine, sulfur dichloride, and phosphorus trichloride. Hildebrandt, B.; Vanni, H.; Heydtmann, H. (Inst. Phys. Theor. Chem., J. W. Goethe-Univ., Frankfurt/Main D-6000/1, Fed. Rep. Ger.Several reagents with their cas registry numbers 10545-99-0 and 7719-12-2 are used here.). Chem. Phys., 84(1), 125-37 (English) 1984. CODEN: CMPHC2. ISSN: 0301-0104. DOCUMENT TYPE: Journal CA Section: 73 (Optical, Electron, and Mass Spectroscopy and Other Related Properties) IR chemiluminescence from HCl was obsd. in arrested relaxation expts. to yield vibrational and rotational distributions from the reactions H + Cl2, SCl2 and PCl3, where H denotes H atoms with translational energy of 0.45 eV. In all 3 reaction systems, the chemiluminescence was attributed to the primary Cl abstraction. Comparison with the results of the thermal processes (0.04 eV H atoms) led to the following conclusions: for H+Cl2, the excess of translational energy is transformed into translational product energy and rotational energy of the mol. HCl; for H + SCl2, the excess of translational energy is transformed mainly into translational energy of the products and perhaps internal energy of SCl; for H + PCl3, the excess of translational energy allows the observation of the primary abstraction reaction, which could in earlier expts. at 300 K not be sepd. from secondary chemiluminescent processes. Bimodal rotational distributions were confirmed for several vibrational states of HCl formed in the systems H + Cl2 and H + SCl2. Bimodal rotational distributions were also detected in the chemiluminescent reaction H(0.04 eV) + CH3SCl ? HCl(v ￡5)+MeS. .