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CAS No.: | 79466-08-3 |
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Name: | menthol glucuronide |
Article Data: | 4 |
Molecular Structure: | |
Formula: | C16H28 O7 |
Molecular Weight: | 332.394 |
Synonyms: | Glucopyranosiduronicacid, l-menthyl, b-D-(6CI); b-D-Glucopyranosiduronic acid, 5-methyl-2-(1-methylethyl)cyclohexyl,[1R-(1a,2b,5a)]-; l-Menthol glucuronide |
Density: | 1.28g/cm3 |
Boiling Point: | 516.3°C at 760 mmHg |
Flash Point: | 184.5°C |
PSA: | 116.45000 |
LogP: | 0.35600 |
(-)-menthyl β-D-glucopyranoside
(-)-Menthol glucuronide
Conditions | Yield |
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With oxygen; sodium hydrogencarbonate; platinum at 60℃; |
(-)-Menthol glucuronide
Conditions | Yield |
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With potassium hydroxide In methanol Ambient temperature; |
(-)-menthol
(-)-Menthol glucuronide
Conditions | Yield |
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Multi-step reaction with 2 steps 1: 46 percent / CdCO3 / toluene / 2 h / Heating 2: KOH / methanol / Ambient temperature View Scheme |
1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester
(-)-Menthol glucuronide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 46 percent / CdCO3 / toluene / 2 h / Heating 2: KOH / methanol / Ambient temperature View Scheme |
(-)-Menthol glucuronide
D-Glucuronic acid
Conditions | Yield |
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With sulfuric acid; water anschl. Erwaermen mit BaCO3, dann mit wss.-aethanol. H2SO4; |
(-)-Menthol glucuronide
Conditions | Yield |
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With β-glucuronidase; acetate buffer at 37℃; hydrolysis; other enzyme (glycyrrhizinic acid hydrolase); |
Conditions | Yield |
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β-glucoronidase II In water at 37℃; for 0.166667h; Product distribution; substrate specifity of enzyme; |