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CAS No.: | 844856-42-4 |
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Name: | 3-broMo-3-chloro-biphenyl |
Article Data: | 1 |
Molecular Structure: | |
Formula: | C12H8BrCl |
Molecular Weight: | 267.553 |
Synonyms: | 3-bromo-3'-chloro-1,1'-biphenyl |
Density: | 1.463±0.06 g/cm3(Predicted) |
Melting Point: | 41 °C |
Boiling Point: | 331.7±17.0 °C(Predicted) |
PSA: | 0.00000 |
LogP: | 4.76950 |
bromobenzene
3-chlorobenzenediazonium tetrafluoroborate
A
3-bromo-3′-chloro-1,1′-biphenyl
B
4-bromo-3'-chloro-1,1'-biphenyl
Conditions | Yield |
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With pyridine at 23℃; for 18h; Gomberg-Bachman Arylation; Inert atmosphere; Irradiation; Overall yield = 90 percent; Overall yield = 144 mg; |
4-dibenzothiophene boronic acid
3-bromo-3′-chloro-1,1′-biphenyl
4-(3'-chloro-[1,1'-biphenyl]-3-yl)dibenzo[b,d]thiophene
Conditions | Yield |
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With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 5h; Inert atmosphere; Reflux; | 90% |
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 90℃; for 5h; | 90% |
With tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 80℃; for 7h; Alkaline conditions; Inert atmosphere; | 82% |
3-bromo-3′-chloro-1,1′-biphenyl
9H-carbazole
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 12h; Reflux; | 90% |
Conditions | Yield |
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With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 6h; Reflux; | 73% |
Conditions | Yield |
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With tetrakis(triphenylphosphine) palladium(0); tetrabutyl-ammonium chloride; potassium carbonate In ethanol; water; toluene at 78℃; for 8h; Inert atmosphere; | 72% |
2-([1,1‘:3’,1“-terphenyl]-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
3-bromo-3′-chloro-1,1′-biphenyl
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere; | 70% |
2-([1,1':3′,1''-terphenyl]-5'-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
3-bromo-3′-chloro-1,1′-biphenyl
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere; | 65% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere; | 65% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In 5,5-dimethyl-1,3-cyclohexadiene at 130℃; for 6h; Inert atmosphere; | 59% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 12h; Inert atmosphere; | 55% |