Detail of "96-30-0"

Reference

Selective fungicide

Selective fungicide. Werner, Rolf Dieter; Fieseler, Christine; Schoenfelder, Dietmar; Walek, Wolfgang; Wind, Monika; Kramer, Wilfried; Pallas, Manfred; Steinke, Walter (VEB Chemiekombinat Bitterfeld, Ger. Dem. Rep.). Ger. (East) DD 213586 A1 19 Sep 1984, 9 pp. (German). (German Democratic Republic). CODEN: GEXXA8. CLASS: IC: A01N043-82. APPLICATION: DD 83-248050 18 Feb 1983. DOCUMENT TYPE: Patent CA Section: 5 (Agrochemical Bioregulators) Section cross-reference(s): 28 3,5-Dimercapto-1,2,4-thiadiazoles (I, R = H, alkenyl, alkoxycarbonylmethyl, arylthiomethyl) are fungicides, esp. 95115-09-6 which is the cas registry number is also used here. active against Phytophthora infestans. Thus, 5-mercapto-3-[(N-methylcarbamoyl)methylthio]-1,2,4-thiadiazole (II) [95115-09-6], at 1000 ppm, completely protected tomato leaves from injury by P. infestans and was not phytotoxic. II was prepd. by reaction of di-K cyanimidodithiocarbonate [13145-41-0] with N-methylchloroacetamide [96-30-0]. .

Chromatographic method for determining methylmonochloroacetamide

Chromatographic method for determining methylmonochloroacetamide. Hodisan, Teodor; Marutoiu, Constantin; Brendea, Zoia (Rom.). Rev. Chim. (Bucharest), 29(2), 176 (Romanian) 1978. CODEN: RCBUAU. DOCUMENT TYPE: Journal CA Section: 5 (Agrochemicals) In the synthesis of Dimethoate [60-51-5] the intermediates Me monochloracetate (I) [96-34-4], Me monochloracetamide (II) [96-30-0], and methanol [67-56-1] are present in the reaction mixts. The 3 compds. were detd. by gas chromatog., using 13% dinonyl phthalate on Chromosorb W. The chromatog. max. were identical with those obtained with pure I and II. The pure compds. were obtained by thin-layer chromatog. on silicagel RH with cyclohexane-isopropanol-E acetate (4:2:2 vol./vol.) as eluent. I and II were extd. from the silicagel with CHCl3.