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104091-08-9

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104091-08-9 Usage

Description

Fmoc-D-glutamic acid gamma-tert-butyl ester is a white to light yellow crystalline powder that serves as an essential raw material and intermediate in various fields, including organic synthesis, agrochemicals, and dyestuff.

Uses

Used in Organic Synthesis:
Fmoc-D-glutamic acid gamma-tert-butyl ester is used as a key intermediate for the synthesis of various organic compounds. Its unique structure allows for the creation of complex molecules and contributes to the development of new pharmaceuticals and chemical products.
Used in Agrochemicals:
In the agrochemical industry, Fmoc-D-glutamic acid gamma-tert-butyl ester is utilized as a vital component in the development of pesticides, herbicides, and other agricultural chemicals. Its incorporation enhances the effectiveness and selectivity of these products, leading to improved crop protection and yield.
Used in Dyestuff:
Fmoc-D-glutamic acid gamma-tert-butyl ester is employed as a crucial intermediate in the production of dyes and pigments. Its chemical properties enable the creation of a wide range of colors and hues, contributing to the diversity and vibrancy of the dyestuff industry.

Check Digit Verification of cas no

The CAS Registry Mumber 104091-08-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,0,4,0,9 and 1 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 104091-08:
(8*1)+(7*0)+(6*4)+(5*0)+(4*9)+(3*1)+(2*0)+(1*8)=79
79 % 10 = 9
So 104091-08-9 is a valid CAS Registry Number.
InChI:InChI=1/C24H27NO6/c1-24(2,3)31-21(26)13-12-20(22(27)28)25-23(29)30-14-19-17-10-6-4-8-15(17)16-9-5-7-11-18(16)19/h4-11,19-20H,12-14H2,1-3H3,(H,25,29)(H,27,28)/t20-/m1/s1

104091-08-9 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
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  • TCI America

  • (B3669)  5-tert-Butyl N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-D-glutamate Hydrate  >98.0%(HPLC)(T)

  • 104091-08-9

  • 1g

  • 490.00CNY

  • Detail
  • TCI America

  • (B3669)  5-tert-Butyl N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-D-glutamate Hydrate  >98.0%(HPLC)(T)

  • 104091-08-9

  • 5g

  • 1,550.00CNY

  • Detail
  • Alfa Aesar

  • (H66624)  N-Fmoc-D-glutamic acid 5-tert-butyl ester, 98%   

  • 104091-08-9

  • 5g

  • 459.0CNY

  • Detail
  • Alfa Aesar

  • (H66624)  N-Fmoc-D-glutamic acid 5-tert-butyl ester, 98%   

  • 104091-08-9

  • 25g

  • 1842.0CNY

  • Detail
  • Sigma-Aldrich

  • (07697)  Fmoc-D-Glu(OtBu)-OH  ≥98.0% (HPLC)

  • 104091-08-9

  • 07697-1G-F

  • 898.56CNY

  • Detail
  • Sigma-Aldrich

  • (07697)  Fmoc-D-Glu(OtBu)-OH  ≥98.0% (HPLC)

  • 104091-08-9

  • 07697-5G-F

  • 3,105.18CNY

  • Detail

104091-08-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name N-Alpha-Fmoc-D-Glutamic Acid Gamma-T-Butyl Ester

1.2 Other means of identification

Product number -
Other names 5-tert-Butyl N-Fmoc-D-glutamate Hydrate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:104091-08-9 SDS

104091-08-9Relevant articles and documents

Supported Catalytically Active Supramolecular Hydrogels for Continuous Flow Chemistry

Rodon Fores, Jennifer,Criado-Gonzalez, Miryam,Chaumont, Alain,Carvalho, Alain,Blanck, Christian,Schmutz, Marc,Serra, Christophe A.,Boulmedais,Schaaf, Pierre,Jierry, Lo?c

supporting information, p. 18817 - 18822 (2019/11/16)

Inspired by biology, one current goal in supramolecular chemistry is to control the emergence of new functionalities arising from the self-assembly of molecules. In particular, some peptides can self-assemble and generate exceptionally catalytically active fibrous networks able to underpin hydrogels. Unfortunately, the mechanical fragility of these materials is incompatible with process developments, relaying this exciting field to academic curiosity. Here, we show that this drawback can be circumvented by enzyme-assisted self-assembly of peptides initiated at the walls of a supporting porous material. We applied this strategy to grow an esterase-like catalytically active supramolecular hydrogel (CASH) in an open-cell polymer foam, filling the whole interior space. Our supported CASH material is highly efficient towards inactivated esters and enables the kinetic resolution of racemates. This hybrid material is robust enough to be used in continuous flow reactors, and is reusable and stable over months.

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