111258-23-2 Usage
Chemical Properties
White to slightly yellow crystalline powder
Uses
Different sources of media describe the Uses of 111258-23-2 differently. You can refer to the following data:
1. reactant in [3+2] annulation reactions 1 reactant in preparation of inhibitors of mammalian secreted phospholipases A2 2 reactant in Heck reactions 3 reactant in preparation of indole fatty alcohol derivatives 4 reactant in methylation reactions.
2. reactant in [3+2] annulation reactionsreactant in preparation of inhibitors of mammalian secreted phospholipases A2reactant in Heck reactionsreactant in preparation of indole fatty alcohol derivativesreactant in methylation reactions
General Description
Methyl 4-methoxy-2-indolecarboxylate is an indole derivative.
Check Digit Verification of cas no
The CAS Registry Mumber 111258-23-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,1,2,5 and 8 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 111258-23:
(8*1)+(7*1)+(6*1)+(5*2)+(4*5)+(3*8)+(2*2)+(1*3)=82
82 % 10 = 2
So 111258-23-2 is a valid CAS Registry Number.
InChI:InChI=1/C11H11NO3/c1-14-10-5-3-4-8-7(10)6-9(12-8)11(13)15-2/h3-6,12H,1-2H3
111258-23-2Relevant articles and documents
A convenient synthesis of benz-1,2-oxazine derivatives
Ghosh, Sukhen Chandra,De, Asish
, p. 979 - 980 (2000)
An expedient synthesis of benz-1,2-oxazine derivatives involving nitrene insertion on a methoxy group is described.
A Bu4N[Fe(CO)3(NO)]-Catalyzed Hemetsberger–Knittel Indole Synthesis
Baykal, Aslihan,Plietker, Bernd
supporting information, (2020/02/20)
The nucleophilic Fe complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of aryl vinyl azides to give the corresponding indole derivatives in good to excellent yields.
Gold(I)-catalyzed rearrangement of alkynylaziridine indoles for the synthesis of spiro-tetrahydro-β-carbolines
Yang, Yan-Fang,Li, Lian-Hua,He, Yu-Tao,Luo, Jian-Yi,Liang, Yong-Min
supporting information, p. 702 - 707 (2014/02/14)
Functionalized spiro-tetrahydro-β-carbolines were formed by an efficient gold(I)-catalyzed rearrangement reaction of alkynylaziridine indoles. The reaction involved a Friedel-Crafts type intramolecular reaction of alkynylaziridine indoles, following by hydroamination of aminoallene intermediate.
