14629-62-0Relevant articles and documents
Mechanism of the dehydrogenative silylation of alcohols catalyzed by cationic gold complexes: An experimental and theoretical study
Labouille, Stephanie,Escalle-Lewis, Aurelie,Jean, Yves,Mezailles, Nicolas,Leafloch, Pascal
, p. 2256 - 2265 (2011)
The catalytic activity both of cationic [(XDPP)Au][X] (XDPP=bis-2,5- diphenylphosphole xantphos X=BF4) and of the isolated gold hydride complex [(XDPP)2Au2H][OTf] in the dehydrogenative silylation process is presented. A p
Chemoselective Deoxygenation of 2° Benzylic Alcohols through a Sequence of Formylation and B(C6F5)3-Catalyzed Reduction
Oestreich, Martin,Richter, Sven C.
supporting information, p. 2103 - 2106 (2021/07/22)
A sequence of formylation and B(C6F5)3-catalyzed reduction of the resulting formate with Et3SiH enables the chemoselective deoxygenation of secondary benzylic alcohols. Primary benzylic and tertiary non-benzylic alcohols are not reduced by this protocol. The formyl group fulfills a double role as activator and self-sacrificing protecting group. The deoxygenation of these formates is fast and can be carried out in the presence of other potentially reducible groups. Neighboring-group participation was found in the deoxygenation of certain diol motifs.
Hydrosilylation of Carbonyls Catalyzed by Hydridoborenium Borate Salts: Lewis Acid Activation and Anion Mediated Pathways
Rawat, Sandeep,Bhandari, Mamta,Porwal, Vishal Kumar,Singh, Sanjay
supporting information, p. 7195 - 7203 (2020/05/18)
The electronically unsaturated three-coordinated hydridoborenium cations [LBH]+[HB(C6F5)3]-(1) and [LBH]+[B(C6F5)4]-(2), supported by a bis(phosphinimino)amide ligand, were found to be excellent catalysts for hydrosilylation of a range of aliphatic and ar