185067-05-4Relevant articles and documents
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Mowry
, p. 189-222, 246-283 (1948)
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Asymmetric cyanation of activated olefins with ethyl cyanoformate catalyzed by a modular titanium catalyst
Wang, Jun,Li, Wei,Liu, Yanling,Chu, Yangyang,Lin, Lili,Liu, Xiaohua,Feng, Xiaoming
supporting information; experimental part, p. 1280 - 1283 (2010/06/15)
"Chemical Equation Presented" Asymmetric cyanation of a class of easily available olefins with a favorable cyanide source ethyl cyanoformate (CNCOOEt) was realized by an interesting modular catalyst. High yields and ee values were obtained for a range of substrates under solvent-free and mild reaction conditions. The products obtained could be easily transformed to the enantioenriched useful intermediates 5,6, and pharmaceutically Important γ-aminobutyric acid 7.
NOVEL HETEROCYCLES BY THE MALONIC ESTER VARIATION OF THE JAPP-KLINGEMANN REACTION
Heckendorn, Roland
, p. 921 - 944 (2007/10/02)
Azocompounds prepared by coupling malonic ester derivatives with diazotized anilines, 3-amino-2-chloropyridine, anthranilic ester or 2-aminobenzophenones are shown to be versatile intermediates for the synthesys of various polyaza-heterocycles.