19780-10-0Relevant articles and documents
SELENOESTERS IN ORGANIC SYNTHESIS. 2. NEW SYNTHESIS OF SATURATED AND α,β-UNSATURATED KETONES AND THE SYNTHESIS OF THE PEACH MOTH PHEROMONE (Carposia niponensis)
Sviridov, A. F.,Ermolenko, M. S.,Yashunskii, D. V.,Kochetkov, N. K.
, p. 1514 - 1518 (1985)
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Selective Ketone Formations via Cobalt-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols
Pandey, Bedraj,Xu, Shi,Ding, Keying
supporting information, p. 7420 - 7423 (2019/10/02)
A homogeneous cobalt-catalyzed β-alkylation of secondary alcohols with primary alcohols to selectively synthesize ketones via acceptorless dehydrogenative coupling is reported for the first time. Notably, this transformation is environmentally benign and atom economical with water and hydrogen gas as the only byproducts.
Simple one pot synthesis of ketone from carboxylic acid using DCC as an activator
Mekonnen, Habtamu Gelaw,Jana, Samaresh
supporting information, p. 1382 - 1384 (2019/04/30)
Simple one pot procedure for the conversion of carboxylic acid to ketone is described. Various carboxylic acids were converted to the corresponding ketones in excellent manner in presence of N,N′-dicyclohexylcarbodiimide (DCC) and organometallic reagents. Aromatic, heteroaromatic and aliphatic acids were converted to the corresponding ketones smoothly under the optimum conditions using organolithium reagents. In this process, desired products have been isolated from the crude reaction mixtures in moderate yields during the purification process.
Nickel-catalyzed cross-coupling of non-activated and functionalized alkyl halides with alkyl grignard reagents
Vechorkin, Oleg,Hu, Xile
supporting information; experimental part, p. 2937 - 2940 (2009/09/08)
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