1010689-19-6Relevant articles and documents
Fine-tuning of boron complexes with cage-shaped ligand geometry: Rational design of triphenolic ligand as a template for structure control
Yasuda, Makoto,Yoshioka, Sachiko,Nakajima, Hideto,Chiba, Kouji,Baba, Akio
, p. 929 - 932 (2008)
Boron complexes surrounded with organic cages were controlled precisely by a remote atom placed at the bottom of the cage. A replacement of the bottom tether atom (carbon or silicon) changed the characteristics (kinetic and thermodynamic factors) of boron complexes by geometric effects. A theoretical study shows that the bottom atoms also control eigenvalues of MO. This cage complex will provide a systematic template for fine-tuning of metal complexes to create various properties.