7305-04-6

Basic information

• Product Name: o-bromophenyl N,N-dimethylcarbamate
• Synonyms: o-bromophenyl N,N-dimethylcarbamate
• CAS NO: 7305-04-6
• Molecular Weight: 244.088
• Mol File: 7305-04-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: o-bromophenyl N,N-dimethylcarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: o-bromophenyl N,N-dimethylcarbamate(7305-04-6)
• EPA Substance Registry System: o-bromophenyl N,N-dimethylcarbamate(7305-04-6)

Safety Data

• Hazardous Substances Data: 7305-04-6(Hazardous Substances Data)

Upstream product

• 95-56-7 2-hydroxybromobenzene 
• 68-12-2 N,N-dimethyl-formamide 
• 108-95-2 phenol 
• 6969-90-0 phenyl N,N-dimethylcarbamate 

Downstream Products

• 1010689-27-6 tris(2-(N,N-dimethylcarbamoyloxy)phenyl)(methyl)silane 
• 1010689-28-7 tris(2-(N,N-dimethylcarbamoyloxy)phenyl)(isobutyl)silane 
• 2040-86-0 2-bromo-6-iodophenol 
• 1534364-16-3 2-bromo-6-chlorophenyl dimethylcarbamate 
• 608-33-3 2,6-dibromophenol 
• 2040-88-2 2-bromo-6-chlorophenol 
• 1375931-46-6 2,6-dibromophenyl dimethylcarbamate 
• 1010689-19-6 tris(2-hydroxyphenyl)(isobutyl)silane 
• 1010689-17-4 tris(2-hydroxyphenyl)(methyl)silane 

Relevant articles and documents

Rhodium-Catalyzed ortho-Bromination of O-Phenyl Carbamates Accelerated by a Secondary Amide-Pendant Cyclopentadienyl Ligand

It has been established that a newly developed cyclopentadienyl rhodium(III) [CpARhIII] complex, bearing an acidic secondary amide moiety on the Cp ring, is able to catalyze the ortho-bromination of O-phenyl carbamates with N-bromosuccinimide (NBS) at room temperature. The presence of the acidic secondary amide moiety on the CpA ligand accelerates the bromination by the hydrogen bond between the acidic NH group of the CpA ligand and the carbonyl group of NBS.

Palladium catalyzed C-H functionalization of O-arylcarbamates: Selective ortho -bromination using NBS

A series of cyclometalated palladium complexes derived from O-phenylcarbamates has been synthesized by the reaction of the respective carbamates with Pd(OAc)2 in the presence of acids, CF 3CO2H, CF3SO3/sub