102692-33-1

Basic information

• Product Name: 2-Propen-1-one, 1-[4-(1,1-dimethylethyl)phenyl]-3-phenyl-, (E)-
• CAS NO: 102692-33-1
• Molecular Formula: C19H20O
• Molecular Weight: 264.367
• Mol File: 102692-33-1.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 1-[4-(1,1-dimethylethyl)phenyl]-3-phenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 1-[4-(1,1-dimethylethyl)phenyl]-3-phenyl-, (E)-(102692-33-1)
• EPA Substance Registry System: 2-Propen-1-one, 1-[4-(1,1-dimethylethyl)phenyl]-3-phenyl-, (E)-(102692-33-1)

Safety Data

• Hazardous Substances Data: 102692-33-1(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 6783-05-7 trans-2-phenylvinylboronic acid 
• 52436-75-6 (4-tert-butylphenyl)diazonium tetrafluoroborate 
• 100-42-5 styrene 
• 35779-04-5 1-tert-butyl-4-iodobenzene 
• 5153-67-3 nitrostyrene 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 536-74-3 phenylacetylene 
• 1567388-38-8 1-(4-tert-butylphenyl)-3-phenylprop-2-yn-1-ol 
• 772-38-3 4-tert-Butylphenylacetylene 
• 100-52-7 benzaldehyde 
• 82102-37-2 9-methyl-9H-fluorene-9-carbonyl chloride 
• 943-27-1 4'-t-butylacetophenone 

Downstream Products

• 43008-76-0 1-(4-(tert-butyl)phenyl)-3-phenylpropane-1-one 

Relevant articles and documents

Ligand and substrate π-stacking interaction controlled enantioselectivity in the asymmetric aziridination

Both the steric hindrance and the electronic effect are important factors for controlling the enantioselectivity in asymmetric catalysis. The substituent-dependent enantioselectivity in the asymmetric aziridination of chalcones catalyzed by 1,8-anthracene

Palladium-imidazolium-catalyzed carbonylative coupling of aryl diazonium ions and aryl boronic acids

Palladium(II) acetate and N,N-bis-(2,6-diisopropylphenyl)dihydroimidazolium chloride (2 mol%) were used to catalyze the carbonylative coupling of aryl diazonium tetrafluoroborate salts and aryl boronic acids to form aryl ketones. Optimal conditions includ

DBU-Catalyzed Rearrangement of Secondary Propargylic Alcohols: An Efficient and Cost-Effective Route to Chalcone Derivatives

A 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)-catalyzed rearrangement of diarylated secondary propargylic alcohols to give α,β-unsaturated carbonyl compounds has been developed. The typical 1,3-transposition of oxy functionality, characteristic of Mayer-Schuster rearrangements, is not observed in this case. A broad substrate scope, functional-group tolerance, operational simplicity, complete atom economy, and excellent yields are among the prominent features of the reaction. Additionally, the photophysical properties and crystal-structure-packing behavior of selected compounds were investigated and found to be of interest.

Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels-Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts

A novel cationic silicon-sulfur Lewis pair with a chiral H8-binaphthyl backbone is reported. It catalyzes otherwise sluggish Diels-Alder reactions of cyclohexa-1,3-diene and chalcone derivatives in good yields and decent enantioselectivities (up to 81% ee). The enantioinduction is highest with a [1,1′-biphenyl]-4-yl substituent at the carbonyl carbon atom. This moiety can be later converted into a carboxyl group by Baeyer-Villiger oxidation. The same oxidant also epoxidizes the double bond in the cycloadduct, and the epoxide engages in a lactonization with the carboxylic acid. Synthetically interesting hexahydro-3,6-methanobenzofuran-2(3H)-one skeletons are obtained in one pot.