103440-12-6Relevant articles and documents
Diastereofacial selectivity in uncatalyzed Diels-Alder cycloadditions involving α,β-unsaturated esters and lactones with stereogenic centers containing oxygen functiionalities
Casas, Ramon,Parella, Teodor,Branchadell, Vicenc,Oliva, Antonio,Ortuno, Rosa M.,Guingant, Andre
, p. 2659 - 2680 (2007/10/02)
Both experimental and theoretical studies on the Diels-Alder cycloadditions of dienophiles 1, 2 and 3 to different dienes show that the observed diastereofacial selectivity results from a combination of electronic and steric interactions. The traditional