10606-63-0

Basic information

• Product Name: 1(R)-methyl-2(S)-phenylcyclopropanol
• Synonyms: 1(R)-methyl-2(S)-phenylcyclopropanol
• CAS NO: 10606-63-0
• Molecular Weight: 148.205
• Mol File: 10606-63-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1(R)-methyl-2(S)-phenylcyclopropanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1(R)-methyl-2(S)-phenylcyclopropanol(10606-63-0)
• EPA Substance Registry System: 1(R)-methyl-2(S)-phenylcyclopropanol(10606-63-0)

Safety Data

• Hazardous Substances Data: 10606-63-0(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 79-20-9 acetic acid methyl ester 
• 141-78-6 ethyl acetate 
• 10606-44-7 trans-1-methyl-1-acetoxy-2-phenylcyclopropane 
• 3277-89-2 phenethylmagnesium bromide 
• 10152-79-1 (+)-1-methyl-trans-2-phenylcyclopropanecarboxylic acid 
• 10152-79-1 (1R,2S)-1-methyl-2-phenyl-cyclopropanecarboxylic acid 
• 10606-65-2 Aethyl 4-chloro-2-methyl-4-phenyl-butanoat 
• 10606-44-7 (-)-cis-1-Methyl-2-phenylcyclopropylacetat 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 10606-64-1 3-methyl-5-phenyl-tetrahydrofuran-2-one 

Downstream Products

• 82323-82-8 4-oxo-2-phenylpentanenitrile 
• 52306-30-6 1-Brom-1-phenyl-3-oxo-butan 
• 1027564-45-9 5-hydroxy-5-methyl-3-phenyl-4,5-dihydro-2-isoxazole 

Relevant articles and documents

Enantioselective Copper-Catalyzed Radical Ring-Opening Cyanation of Cyclopropanols and Cyclopropanone Acetals

A novel approach for enantioselective cyanation of cyclopropanols and their derivatives through copper-catalyzed radical relay processes has been developed. Various cyclopropanols and cyclopropanone acetals are compatible to the catalytic conditions, providing β-carbonyl nitriles with excellent enantioselectivity. These products can be readily converted to chiral γ-amino acids derivatives and drugs such as (R)-baclofen. Preliminary mechanistic studies have supported a ring-opening process for cyclopropanoxy radicals followed by copper-catalyzed enantioselective cyanation of benzylic radicals to form the C?CN bonds in an enantioselective manner. (Figure presented.).

Diastereoselective synthesis of cis-1,2-disubstituted cyclopropanols and cyclopent-3-enols via SmI2 mediated C-N(Bt) bond cleavage

Abstract Diastereoselective synthesis of cis-1,2-disubstituted cyclopropanols and cyclopent-3-enols has been achieved from readily available β-benzotriazolyl ketones (β-Bt ketones) via a C-N(Bt) bond cleavage/cyclization process promoted by SmI2/sub

Electrochemically Promoted Cyclocoupling of 1,3-Dienes or Styrenes with Aliphatic Carboxylic Esters

The cathodic cyclocoupling of 1,3-dienes 1 with aliphatic esters 2 is promoted by a magnesium electrode and yields homologs of 3-cyclopentenol.Under similar reaction conditions, the coupling of styrenes with 2 affords 2-phenylcyclopropanol derivatives, an