107-37-9

Basic information

• Product Name: ALLYLTRICHLOROSILANE
• Synonyms: 3-TRICHLOROSILYLPROPENE;ALLYLTRICHLOROSILANE;TRICHLOROALLYLSILANE;Allyl trichlorosilane, stabilized;allylsilicone;allylsiliconetrichloride;allyltrichloro-silan;allyltrichlorosilane,stabilized
• CAS NO: 107-37-9
• Molecular Formula: C₃H₅Cl₃Si
• Molecular Weight: 175.52
• EINECS: 203-485-9
• Product Categories: Functional Materials;Si (Classes of Silicon Compounds);Si-Cl Compounds;Silane Coupling Agents;Trichlorosilanes;Vinyl Silanes (Silane Coupling Agents);Vinylsilanes, Allylsilanes;Protecting and Derivatizing Reagents;Self Assembly&Contact Printing;Self-Assembly Materials;SilanesProtection and Derivatization;Silicon-Based;Protection and Derivatization
• Mol File: 107-37-9.mol
• Article Data: 20

Chemical Properties

• Melting Point: 35℃
• Boiling Point: 116 °C750 mm Hg(lit.)
• Flash Point: 88 °F
• Appearance: Clear colorless to slightly yellow/Liquid
• Density: 1.211 g/mL at 25 °C(lit.)
• Vapor Density: >1 (vs air)
• Vapor Pressure: 10 mm Hg ( 16.1 °C)
• Refractive Index: n20/D 1.443(lit.)
• Storage Temp.: Flammables area
• Solubility: soluble in MeCN, THF, CH2Cl2, toluene, benzene, etc.; not compatible with protic solvents, acetone, and other ketones. Dipolar aprotic solvents (DMF, DMSO, HMPA, etc.) coordinate Si, thereby increasing the reactivity of C3H5SiCl3 with electrophiles.
• Water Solubility: Soluble in THF, toluene, benzene. Reacts with water.
• Sensitive: Moisture Sensitive
• BRN: 1743449
• CAS DataBase Reference: ALLYLTRICHLOROSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYLTRICHLOROSILANE(107-37-9)
• EPA Substance Registry System: ALLYLTRICHLOROSILANE(107-37-9)

Safety Data

• Hazard Codes: F,C
• Statements: 11-34
• Safety Statements: 16-26-33-36/37/39-43-45
• RIDADR: UN 1724 8/PG 2
• WGK Germany: 1
• RTECS: VV1530000
• F: 10-21
• TSCA: Yes
• HazardClass: 8
• PackingGroup: II
• Hazardous Substances Data: 107-37-9(Hazardous Substances Data)

Usage

Chemical Description

Allyltrichlorosilane is an organosilicon compound used as a reagent.

InChI:InChI=1/C3H5Cl3Si/c1-2-3-7(4,5)6/h2H,1,3H2

Upstream product

• 463-49-0 1,2-propanediene 
• 1730-25-2 allylmagnesium bromide 
• 107-05-1 3-chloroprop-1-ene 
• 78-88-6 2,3-Dichloroprop-1-ene 
• 26198-63-0 1,2-Dichloropropane 
• 13465-77-5 hexachlorodisilane 
• 10038-98-9 germaniumtetrachloride 
• 10025-78-2 trichlorosilane 
• 346713-20-0 allylsamarium bromide 
• 4873-09-0 allyl tosylate 
• 674-82-8 4-methyleneoxetan-2-one 
• 75-94-5 trichlorovinylsilane 
• 7787-88-4 (n-pr-1-Cl)SiCl₃ 
• 2550-06-3 3-chloropropyltrichlorosilane 

Downstream Products

• 2550-04-1 allyltriethoxysilane 
• 5929-71-5 triacetoxyallylsilane 
• 2551-83-9 allyltrimethoxysilane 
• 1873-92-3 allyldichloromethylsilane 
• 85551-57-1 (R)-1-Phenylbut-3-en-1-ol 
• 60340-28-5 1-phenylhex-5-en-3-ol 
• 52034-17-0 Diphenyl-(3-trichlorosilanyl-propyl)-phosphane 
• 118723-46-9 allyltris(2-methoxyphenyl)silane 
• 40575-42-6 1-octen-4-ol 
• 13891-95-7 (1E,3R)-1-phenyl-1,5-hexadien-3-ol 
• 172925-28-9 trans-(S)-1-phenyl-1,5-hexadien-3-ol 
• 60340-28-5 (S)-1-phenyl-5-hexen-3-ol 
• 80735-94-0 1-Phenyl-3-buten-1-ol 
• 94340-22-4 (R)-1-cyclohexyl-3-buten-1-ol 

Relevant articles and documents

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METHOD FOR THE DEHYDROGENATION OF DICHLOROSILANE

Dichlorosilane and trichlorosilane are dehydrogenated at elevated temperature in the presence of an ammonium or phosphonium salt as a catalyst, and a halogenated hydrocarbon or hydrogen halide. The method may be used to synthesize organochlorosilane.

PRODUCTION METHOD FOR LINEAR AND CYCLIC TRISILAALKANE

The present invention relates to a preparation method for a linear or cyclic trisilaalkane which is a substance useful in the preparation of polycarbosilane and silicon carbide precursors. Linear or cyclic trisilaalkane and organic trichlorosilane derivatives can be synthesized simultaneously and in high yield by reacting bis(chlorosily)methane having a Si—H bond, either alone or together with an organic chloride, using a quaternary organic phosphonium salt compound as a catalyst. Further, since the catalyst can be recovered after use, the present invention is very economical and is thus effective for mass-producing precursors for organic/inorganic hybrid substances.

Processes for manufacturing organochlorosilanes and dipodal silanes and silanes made thereby

Processes are provided for producing organchlorosilanes and dipodal silanes in which an organic halide or alkene or chloralkene is reacted with a hydridochlorosilane in the presence of a quarternary phosphonium salt catalyst by providing sufficient heat to effect a dehydrohalogenative coupling reaction and/or a hydrosilylation reaction and venting the reaction to control reaction pressure and to remove gaseous byproducts from the reaction. The processes are preferably continuous using a catalyst in fluid form at reaction pressures not exceeding about 600 psi. The reactions may be carried out substantially isothermally and/or isobarically, for example in a plug flow reactor or continuous stirred tank reactor. The processes may produce novel silylated compounds including 1,2-bis(trichlorosilyl)decane or 1,2-bis(trimethoxysilyl)decane.