113890-37-2Relevant articles and documents
Structure-based rationalization of aldolase-catalyzed asymmetric synthesis
Liu, Junjie,DeSantis, Grace,Wong, Chi-Huey
, p. 643 - 645 (2002)
This paper describes a structure-based approach to elucidate the stereospecificity, including inversion of enantioselectivity, of the 2-deoxyribose-5-phosphate aldolase-catalyzed asymmetric aldol addition reaction using unnatural substrates designed for t
Improved and practical synthesis of 2-deoxy-l-ribose by hypophosphite-mediated deoxygenation
Chen, Li-Li,Ming, Xun,Cen, Jun-Da
experimental part, p. 1 - 7 (2011/10/31)
An improved and practical route for a large-scale synthesis of 2-deoxy-L-ribose starting from L-arabinose has been developed. This is the first reported synthesis of 2-deoxy-L-ribose in which deoxygenation has been mediated by hypophosphite reagents instead of by organotin reagents.
A new synthetic strategy for 2-deoxy-D-ribose via palladium(II)-catalyzed cyclization of aldehyde
Miyazawa, Masahiro,Awasaguchi, Ken-Ichiro,Uoya, Ikuyo,Yokoyama, Hajime,Hirai, Yoshiro
, p. 1891 - 1902 (2011/04/12)
We achieved a total synthesis of 2-deoxy-D-ribose through intramolecular Pd(II)-catalyzed cyclization of aldehyde via an unstable hemiacetal intermediate as a key step. The Japan Institute of Heterocyclic Chemistry.