1144029-01-5

Basic information

• Product Name: 2-nitro-5-(2-propargyloxy)benzyl alcohol
• Synonyms: 2-nitro-5-(2-propargyloxy)benzyl alcohol
• CAS NO: 1144029-01-5
• Molecular Weight: 207.186
• Mol File: 1144029-01-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-nitro-5-(2-propargyloxy)benzyl alcohol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-nitro-5-(2-propargyloxy)benzyl alcohol(1144029-01-5)
• EPA Substance Registry System: 2-nitro-5-(2-propargyloxy)benzyl alcohol(1144029-01-5)

Safety Data

• Hazardous Substances Data: 1144029-01-5(Hazardous Substances Data)

Upstream product

• 478964-96-4 2-nitro-5-(prop-2-yn-1-yloxy)benzaldehyde 
• 42454-06-8 2-nitro-5-hydroxybenzaldehyde 
• 60463-12-9 3-hydroxymethyl-4-nitrophenol 
• 106-96-7 propargyl bromide 

Downstream Products

• 1379457-36-9 5-propargyl-2-nitrobenzyl carbamate 
• 1379457-35-8 5-propargylether-2-nitrobenzyl carbamate 
• 1318075-32-9 2-nitro-5-(2-propynyloxy)benzyl 4-cyano-4-(phenylcarbonothioylthio)pentanoate 

Relevant articles and documents

Highly ordered nanoporous thin films from photocleavable block copolymers

Poly(styrene-block-ethylene oxide) with an o-nitrobenzyl ester photocleavable junction (PS-hν-PEO) was synthesized by a combined RAFT polymerization and click chemistry approach and represents the first report utilizing this method for the synthesis of photocleavable block copolymers. After solvent annealing, highly ordered thin films were prepared from PS-hν-PEO. Following a very mild UV exposure and successive washing with water, PS-hν-PEO thin films were transformed into highly ordered nanoporous thin PS films with pore diameters of 15-20 nm and long range ordering (over 2 μm × 2 μm). Afterwards the pores were filled with PDMS by spin-coating in combination with capillary forces. After treatment with oxygen plasma to remove the PS templates, highly ordered arrays of silica nanodots were obtained. This represents the first template application example from highly ordered nanoporous thin films derived from block copolymers featuring a photocleavable junction.

Photo- and pH-Responsive Polycarbonate Block Copolymer Prodrug Nanomicelles for Controlled Release of Doxorubicin

Photo/pH dual-responsive amphiphilic diblock copolymers with alkyne functionalized pendant o-nitrobenzyl ester group are synthesized using poly(ethylene glycol) as a macroinitiator. The pendant alkynes are functionalized as aldehyde groups by the azide-al

Light-Triggered Release of Biomolecules from Diamond Nanowire Electrodes

The controlled release of biomolecules from a substrate surface is a challenging task. Photocleavable linkers appear as attractive candidates for light-triggered delivery. We show here the possibility of creating photoactivable diamond nanowire interfaces

CHEMOSELECTIVE THIOL-CONJUGATION WITH ALKENE OR ALKYNE-PHOSPHONAMIDATES

Disclosed are novel conjugates and processes for the preparation thereof. A process for the preparation of alkene- or alkyne-phosphonamidates comprises the steps of (I) reacting a compound of formula (III), with an azide of formula (IV), to prepare a compound of formula (V), reacting a compound of formula (V) with a thiol-containing molecule of formula (VI), resulting in a compound of formula (VII).