115693-78-2

Basic information

• Product Name: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose
• CAS NO: 115693-78-2
• Molecular Weight: 380.438
• Mol File: 115693-78-2.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(115693-78-2)
• EPA Substance Registry System: 3-O-(4-Methoxybenzyl)-1,2:5,6-di-O-isopropylidene-α-D-allofuranose(115693-78-2)

Safety Data

• Hazardous Substances Data: 115693-78-2(Hazardous Substances Data)

Upstream product

• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 937184-70-8 2-(4-methoxybenzyloxy)-4-methylquinoline 
• 14686-89-6 (1,2:5,6)-di-O-isopropylidene-D-gulose 
• 824-94-2 p-methoxybenzyl chloride 
• 2746-25-0 p-Methoxybenzyl bromide 
• 2595-05-3 Diacetone D-glucose 
• 105-13-5 4-Methoxybenzyl alcohol 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 1450734-54-9 4-methoxybenzyl N-phenyl-2,2,2-trifluoroacetimidate 
• 99605-27-3 3-O-(tert-butyldimethylsilyl)-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 13964-22-2 3-O-benzoyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 350848-02-1 2-[(4-methoxybenzyl)oxy]-3-nitropyridine 

Downstream Products

• 109536-51-8 1,2-O-isopropylidene-3-O-(4-methoxybenzyl)-α-D-glucofuranose 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 123-11-5 4-methoxy-benzaldehyde 
• 1021878-07-8 C₂₀H₂₆⁽²⁾H₂O₇ 
• 1379680-87-1 (3R,4S)-4-(4-methoxybenzyloxy)pent-1-en-3-ol 
• 1379680-85-9 (3R,4S)-4-(4-methoxybenzyloxy)pent-1-en-3-yl (3R)-3-hydroxybutanoate 
• 1379680-83-7 (2R)-4-[(3R,4S)-4-(4-methoxybenzyloxy)pent-1-en-3-yloxy]-4-oxobutan-2-yl (4R,5S,E)-5-(acryloyloxy)-4-(tert-butyldimethylsilyloxy)hex-2-enoate 
• 1379680-97-3 C₂₉H₄₂O₇SSi 
• 1379680-86-0 2-tosylethyl (4R,5S,E)-4-(tert-butyldimethylsilyloxy)-5-(4-methoxybenzyloxy)hex-2-enoate 

Relevant articles and documents

P-Methoxybenzyl-N-phenyl-2,2,2-trifluoroacetimidate: A versatile reagent for mild acid catalyzed etherification

PMB-NPTFA 1a is a new month bench stable and powerful reagent for the formation of PMB ethers. Several alcohols were protected in high yields and short reaction times, using low reagent loading and small catalytic amounts of Bi(OTf)3. The mild

An efficient means for generating p-methoxybenzyl (PMB) ethers under mildly acidic conditions

The protection of a wide variety of alcohols as their p-methoxybenzyl ethers can be performed with PMBO-lepidine in the presence of methyl tosylate or, preferably, camphorsulfonic acid. No inorganic promoters are required, thereby facilitating workup and product isolation. Georg Thieme Verlag Stuttgart.

An efficient method for the p-methoxybenzylation of hydroxy groups with 2-(4-methoxybenzyloxy)-3-nitropyridine

2-(4-Methoxybenzyloxy)-3-nitropyridine (PMBONPy), easily prepared from 2-chloro-3-nitropyridine and p-methoxybenzyl (PMB) alcohol, reacts with various types of hydroxy groups in the presence of a catalytic amount of trimethylsilyl triflate (Me3SiOTf) to give the corresponding PMB ethers in high yields under mild conditions.