1195113-90-6

Basic information

• Product Name: (R)-4-(3-hydroxybutyl)-4-hydroxy-2,5-cyclohexadien-1-one
• Synonyms: (R)-4-(3-hydroxybutyl)-4-hydroxy-2,5-cyclohexadien-1-one
• CAS NO: 1195113-90-6
• Molecular Weight: 182.219
• Mol File: 1195113-90-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-4-(3-hydroxybutyl)-4-hydroxy-2,5-cyclohexadien-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-(3-hydroxybutyl)-4-hydroxy-2,5-cyclohexadien-1-one(1195113-90-6)
• EPA Substance Registry System: (R)-4-(3-hydroxybutyl)-4-hydroxy-2,5-cyclohexadien-1-one(1195113-90-6)

Safety Data

• Hazardous Substances Data: 1195113-90-6(Hazardous Substances Data)

Upstream product

• 1482494-94-9 C₁₆H₂₈O₃Si 
• 1482494-93-8 C₁₆H₂₈O₂Si 
• 1482494-92-7 C₂₂H₄₂O₂Si₂ 
• 129752-69-8 (R)-(+)-4-(4'-hydroxyphenyl)-2-butyl acetate 
• 69617-84-1 rac-rhododendrol 
• 5471-51-2 4-(4-hydroxyphenyl)-2-oxobutane 
• 59092-94-3 (R)-rhododendrol 

Relevant articles and documents

Cephalosporolide B serving as a versatile synthetic precursor: Asymmetric biomimetic total syntheses of cephalosporolides C, E, F, G, and (4-OMe-)G

Cephalosporolide B (Ces-B) was efficiently synthesized and exploited for the first time as a versatile biomimetic synthetic precursor for the chemical syntheses of not only cephalosporolides C, G, and (4-OMe-) G via a challenging diastereoselective oxa-Michael addition but also the structurally unprecedented cephalosporolides E and F via a novel biomimetic ring-contraction rearrangement. These findings provide the first direct chemical evidence that Ces-B may be the true biosynthetic precursor of cephalosporolides.