1205-64-7

Basic information

• Product Name: 3-Methyldiphenylamine
• Synonyms: N-(3-Methylphenyl)benzenamine;Phenyl(3-methylphenyl)amine;3-Methyldiphenylamine,98%;3-two Methylaniline;1-phenyl-2-(m-tolyl)hydrazine;3-methyl-n-phenyl-benzenamin;N-PHENYL-N-M-TOLYL-AMINE;N-PHENYL-M-TOLUIDINE
• CAS NO: 1205-64-7
• Molecular Formula: C₁₃H₁₃N
• Molecular Weight: 183.25
• EINECS: 214-885-8
• Product Categories: electronic;Amines;Electronic Chemicals;C11 to C38;Nitrogen Compounds
• Mol File: 1205-64-7.mol
• Article Data: 75

Chemical Properties

• Melting Point: 30 °C
• Boiling Point: 315 °C724 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: yellow liquid or crystal
• Density: 1.066 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.000389mmHg at 25°C
• Refractive Index: n20/D 1.635(lit.)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 0.97±0.30(Predicted)
• CAS DataBase Reference: 3-Methyldiphenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyldiphenylamine(1205-64-7)
• EPA Substance Registry System: 3-Methyldiphenylamine(1205-64-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• TSCA: Yes
• Hazardous Substances Data: 1205-64-7(Hazardous Substances Data)

Usage

Chemical Properties

brown to black liquid after melting

InChI:InChI=1/C13H13N/c1-11-6-5-9-13(10-11)14-12-7-3-2-4-8-12/h2-10,14H,1H3

Upstream product

• 16524-22-4 2-(m-tolylamino)benzoic acid 
• 108-86-1 bromobenzene 
• 108-44-1 1-amino-3-methylbenzene 
• 537-92-8 3-Methylacetanilide 
• 73333-80-9 N-(3-Methylphenyl)-N-phenylbenzamide 
• 82880-43-1 N-nitroso(3-methylphenyl)phenylamine 
• 624-31-7 4-tolyl iodide 
• 139-02-6 sodium phenoxide 
• 62-53-3 aniline 
• 106-39-8 bromochlorobenzene 
• 13716-12-6 tri-tert-butyl phosphine 
• 3375-31-3 palladium diacetate 
• 35692-20-7 trimethoxy(m-tolyl)silane 
• 6850-35-7 3-methylcyclohexan-1-amine 

Downstream Products

• 105972-25-6 2-methyl-N⁴-phenylbenzene-1,4-diamine 
• 124729-98-2 4,4′,4″-tris[3-methylphenyl(phenyl)amino]triphenylamine 
• 3652-91-3 2-methyl-9H-carbazole 
• 82880-43-1 N-nitroso(3-methylphenyl)phenylamine 
• 82880-44-2 N,N'-diphenyl-N,N'-bis(3-methylphenyl)hydrazine 
• 110700-05-5 2-Brom-N-phenyl-N-(m-tolyl)acetamid 
• 4316-54-5 N,N-diphenyl-m-toluidine 
• 138143-23-4 1,3,5-Tris[(3-methylphenyl)phenylamino]benzene 
• 80223-29-6 N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,4-phenylenediamine 
• 207345-05-9 4-bromo-4'-(phenyl-m-tolylamino)benmzene 
• 1056199-49-5 N-phenyl-N-(3-methylphenyl)-4-oxo-4-phenylbutanamide 
• 1115314-57-2 (Z)-4-[(3-methylphenyl)phenylamino]-4-oxo-2-butenoic acid 
• 1252047-26-9 (Z)-2-[4-(phenyl-m-tolyl-amino)phenyl]-3-(thiophen-3-yl)acrylonitrile 
• 1351459-41-0 (E)-butyl 3-(N-phenyl-N-m-tolylamino)acrylate 

Related news

A theoretical and experimental investigation of vibrational spectra and electronic transitions on 3-Methyldiphenylamine (cas 1205-64-7) molecule as organic semiconductor07/18/2019

In this study, the structural and spectroscopic investigations of 3-methyldiphenylamine were reported. The molecular geometry was optimized from Density Functional Theory (B3LYP method) using 6-31+G(d,p) basis set on the ground state and the infrared wavenumbers and intensities were predicted by...detailed

Relevant articles and documents

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In Situ Formation of Cationic π-Allylpalladium Precatalysts in Alcoholic Solvents: Application to C-N Bond Formation

We report an efficient Buchwald-Hartwig cross-coupling reaction in alcoholic solvent, in which a low catalyst loading showed excellent performance for coupling aryl halides (I, Br, and Cl) with a broad set of amines, amides, ureas, and carbamates under mild conditions. Mechanistically speaking, in a protic and polar medium, extremely bulky biarylphosphine ligands interact with the dimeric precatalyst [Pd(π-(R)-allyl)Cl]2 to form the corresponding cationic complexes [Pd(π-(R)-allyl)(L)]Cl in situ and spontaneously. The resulting precatalyst further evolves under basic conditions into the corresponding L-Pd(0) catalyst, which is commonly employed for cross-coupling reactions. This mechanistic study highlights the prominent role of alcoholic solvents for the formation of the active catalyst.

(DiMeIHeptCl)Pd: A Low-Load Catalyst for Solvent-Free (Melt) Amination

(DiMeIHeptCl)Pd, a hyper-branched N-aryl Pd NHC catalyst, has been shown to be efficient at performing amine arylation reactions in solvent-free ("melt") conditions. The highly lipophilic environment of the alkyl chains flanking the Pd center serves as lubricant to allow the complex to navigate through the paste-like environment of these mixtures. The protocol can be used on a multi-gram scale to make a variety of aniline derivatives, including substrates containing alcohol moieties.

Synthesis of unsymmetrically substituted triarylaminesviaacceptorless dehydrogenative aromatization using a Pd/C andp-toluenesulfonic acid hybrid relay catalyst

An efficient and convenient procedure for synthesizing triarylamines based on a dehydrogenative aromatization strategy has been developed. A hybrid relay catalyst comprising carbon-supported Pd (Pd/C) andp-toluenesulfonic acid (TsOH) was found to be effective for synthesizing a variety of triarylamines bearing different aryl groups starting from arylamines (diarylamines or anilines), using cyclohexanones as the arylation sources under acceptorless conditions with the release of gaseous H2. The proposed reaction comprises the following relay steps: condensation of arylamines and cyclohexanones to produce imines or enamines, dehydrogenative aromatization of the imines or enamines over Pd nanoparticles (NPs), and elimination of H2from the Pd NPs. In this study, an interesting finding was obtained indicating that TsOH may promote the dehydrogenation.