1221432-97-8

Basic information

• Product Name: 10-methylene-9-(propa-1,2-dienyl)-9,10-dihydroanthracene
• Synonyms: 10-methylene-9-(propa-1,2-dienyl)-9,10-dihydroanthracene
• CAS NO: 1221432-97-8
• Molecular Weight: 230.309
• Mol File: 1221432-97-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 10-methylene-9-(propa-1,2-dienyl)-9,10-dihydroanthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 10-methylene-9-(propa-1,2-dienyl)-9,10-dihydroanthracene(1221432-97-8)
• EPA Substance Registry System: 10-methylene-9-(propa-1,2-dienyl)-9,10-dihydroanthracene(1221432-97-8)

Safety Data

• Hazardous Substances Data: 1221432-97-8(Hazardous Substances Data)

Upstream product

• 24463-19-2 anthracenylmethyl chloride 
• 53915-69-8 allenyltributylstannane 

Relevant articles and documents

Propargylic and allenic carbocycle synthesis through palladium-catalyzed dearomatization reaction

The dearomatization reaction of benzylic chlorides (1a?k), chloromethylnaphthalenes (1l?r), and naphthalene allyl chlorides (3a?d) with allenyltributyltin proceeded smoothly in the presence of Pd(PPh 3)4 catalyst at room temperature to give the corresponding propargylated and/or allenylated dearomatization products (5, 5′; 6, 6′; and 7, respectively) in high to fair yields. The reaction of 1a?k proceeded smoothly in the presence of TBAF, whereas it was not necessary to use TBAF as an additive in the reactions of 1l?k and 3a?d. These reactions provided a new and efficient method for the synthesis of propargylic and allenic carbocycles.