123492-68-2Relevant articles and documents
Acyclic diastereoselection in prochiral radical addition to prochiral olefins
Sibi, Mukund P.,Rheault, Tara R.,Chandramouli, Sithamalli V.,Jasperse, Craig P.
, p. 2924 - 2930 (2002)
The stereochemical preference (syn or anti) when prochiral radicals add to prochiral acceptors is of fundamental interest. The primary focus of this research was to determine which factors influence the relative stereochemistry between the β and γ chiral
1,4-Addition of Dialkylaluminium Chlorides to α,β-Unsaturated Carboxylic Acid Derivatives: a New Synthesis of β-Branched Carboxylic Acids
Kunz, Horst,Pees, Klaus Juergen
, p. 1168 - 1169 (2007/10/02)
A new synthesis of β-branched carboxylic acid derivatives by the 1,4-addition of dialkylaluminium chlorides to α,β-unsaturated N-acyl amides, the oxazolidones (1) and the oxazinone (4), is described.
