1253853-28-9

Basic information

• Product Name: 4-(4-chlorophenylselanyl)-N,N-dimethylbenzenamine
• Synonyms: 4-(4-chlorophenylselanyl)-N,N-dimethylbenzenamine
• CAS NO: 1253853-28-9
• Molecular Weight: 310.685
• Mol File: 1253853-28-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 4-(4-chlorophenylselanyl)-N,N-dimethylbenzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(4-chlorophenylselanyl)-N,N-dimethylbenzenamine(1253853-28-9)
• EPA Substance Registry System: 4-(4-chlorophenylselanyl)-N,N-dimethylbenzenamine(1253853-28-9)

Safety Data

• Hazardous Substances Data: 1253853-28-9(Hazardous Substances Data)

Upstream product

• 20541-49-5 bis(p-chlorophenyl) diselenide 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 20753-53-1 4-chlorobenzeneseleninic acid 
• 121-69-7 N,N-dimethyl-aniline 
• 57878-20-3 p-chlorobenzeneselenenyl chloride 
• 1253853-23-4 4-chlorophenylselenotributylstannane 

Relevant articles and documents

Palladium Complex Immobilized on Magnetic Nanoparticles Modified with 2-Aminopyridine Ligand: A Novel and Efficient Recoverable Nanocatalyst for C–S and C–Se Coupling Reactions

A novel, versatile and efficient magnetically recoverable palladium nanocatalyst [Fe3O4@SiO2/2-aminopyridine-Pd(II)] was fabricated via the immobilization of palladium(II) complex on the surface of magnetic nanoparticles modified with 2-aminopyridine ligand. The structure of the as-fabricated Fe3O4@SiO2/2-aminopyridine-Pd(II) nanocomposite was characterized by a series of spectroscopic techniques including FT-IR, SEM, TEM, EDX, TGA, XRD, VSM and ICP-OES techniques. The Fe3O4@SiO2/2-aminopyridine-Pd(II) nanocomposite was utilized under mild and eco-friendly conditions in C–S and C–Se coupling reactions to afford a vast variety of diaryl sulfides and diaryl selenides with good to excellent yields. This heterogeneous palladium catalyst can be magnetically separated and reused for at least 7 consecutive trials without any reduction in activity. Graphical Abstract: [Figure not available: see fulltext.]

Electrochemical Oxidative C(sp2)–H Bond Selenylation of Activated Arenes

Herein, we report an electrochemical oxidative C(sp2)–H selenylation of activated arenes. The reaction proceeds in an undivided electrochemical cell at Pt-electrodes in the presence of KI as the supporting electrolyte, which could suffer oxidat

DMSO/iodine-catalyzed oxidative C-Se/C-S bond formation: A regioselective synthesis of unsymmetrical chalcogenides with nitrogen- or oxygen-containing arenes

A convenient metal-free and solvent-free iodine-catalyzed regioselective greener protocol to access different types of unsymmetrical chalcogenides with nitrogen- or oxygen-containing arenes through oxidative C-Se/C-S formation via direct C(sp2)-H bond activation was developed. The products were obtained in good to excellent yields using [O or N]-containing arenes, half equiv. of various odorless diorganyl dichalcogenides (S/Se), iodine (20 mol%) as the catalyst and 3 equiv. of DMSO as the oxidant, applying MW irradiation for 10 min.