125582-96-9Relevant articles and documents
Facile Synthesis of α-Keto Acids and Esters by Palladium-Catalyzed Decarboxylation Reactions of Diallyl α-Oxalcarboxylates
Shimizu, Isao,Makuta, Toshiyuki,Oshima, Masato
, p. 1457 - 1460 (2007/10/02)
Reaction of diallyl α-oxalcarboxylates with formic acid in the presence of palladium catalyst gave α-keto acid in good yields.When the reaction was carried out without formic acid, decarboxylation-allylation took place to give allyl β-allyl-α-keto carboxylates.