1269788-52-4

Basic information

• Product Name: C₃₂H₄₂N₂O₄Si
• Synonyms: C₃₂H₄₂N₂O₄Si
• CAS NO: 1269788-52-4
• Molecular Weight: 546.782
• Mol File: 1269788-52-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₃₂H₄₂N₂O₄Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₂H₄₂N₂O₄Si(1269788-52-4)
• EPA Substance Registry System: C₃₂H₄₂N₂O₄Si(1269788-52-4)

Safety Data

• Hazardous Substances Data: 1269788-52-4(Hazardous Substances Data)

Upstream product

• 1269788-51-3 ethyl 2-((3R,4S)-1-benzoyl-3-((tert-butyldimethylsilyloxy)methyl)piperidin-4-yl)acetate 
• 41037-26-7 6-methoxy-4-methylquinoline 

Downstream Products

• 1269788-53-5 C₃₂H₄₂N₂O₃Si 
• 1269788-54-6 C₃₂H₄₄N₂O₅Si 
• 56-54-2 quinindine 
• 56652-53-0 quinidine acetate 

Relevant articles and documents

Organocatalytic asymmetric synthesis of quinine and quinidine

Quinine and quinidine were synthesized by a highly enantio- and stereoselective approach starting from a proline-catalyzed asymmetric cycloaldolization of benzyl bis(2-formylethyl)carbamate which gave a 70:30 mixture of (3R,4R)-N-Cbz-3-hydroxymethyl-4-hydroxypiperidine (96% ee) and its 4S-epimer (92% ee) in 94% yield after in situ NaBH4 reduction.