127410-85-9

Basic information

• Product Name: Benzene, [(3E)-2-methylene-3-decenyl]-
• CAS NO: 127410-85-9
• Molecular Formula: C17H24
• Molecular Weight: 228.378
• Mol File: 127410-85-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(3E)-2-methylene-3-decenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(3E)-2-methylene-3-decenyl]-(127410-85-9)
• EPA Substance Registry System: Benzene, [(3E)-2-methylene-3-decenyl]-(127410-85-9)

Safety Data

• Hazardous Substances Data: 127410-85-9(Hazardous Substances Data)

Upstream product

• 51751-87-2 (E)-1-bromo-1-octene 
• 141694-63-5 (E)-1-iodo-3-phenyl-1-propene 
• 60468-22-6 2-bromo-3-phenyl-propene 
• 111581-72-7 (E)-1-(diisopropoxymethylsilyl)-1-octene 

Relevant articles and documents

Zirconium-Mediated Cross-Coupling of Terminal Alkynes and Vinyl Bromides: Selective Synthesis of Cyclobutene and 1,3-Diene Derivatives

A diastereoselective synthesis of 1,3-butadiene or cyclobutene derivatives by a zirconium-mediated reaction of alkenyllithium compounds and vinyl bromides is reported. The key steps involve the generation of zirconocene-alkyne complexes from haloalkenes and subsequent coupling with alkenyl bromides. Thus, formally the process supposes the cross-coupling reaction between a terminal alkyne and an alkenyl bromide. Moreover, the use of butyl vinyl ether instead of vinyl bromide as the unsaturated system allows an alternative access to different 1,3-butadiene regioisomers.