129533-52-4

Basic information

• Product Name: 5,10-di(4-tolyl)-5,10-dihydrophenazine
• Synonyms: 5,10-di(4-tolyl)-5,10-dihydrophenazine
• CAS NO: 129533-52-4
• Molecular Weight: 362.474
• Mol File: 129533-52-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5,10-di(4-tolyl)-5,10-dihydrophenazine(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10-di(4-tolyl)-5,10-dihydrophenazine(129533-52-4)
• EPA Substance Registry System: 5,10-di(4-tolyl)-5,10-dihydrophenazine(129533-52-4)

Safety Data

• Hazardous Substances Data: 129533-52-4(Hazardous Substances Data)

Upstream product

• 348-54-9 2-Fluoroaniline 
• 624-31-7 4-tolyl iodide 
• 1643-98-7 2-fluoro-N-(p-tolyl)aniline 
• 92-82-0 Phenazin 
• 613-32-1 5,10-dihydrophenazine 
• 18440-53-4 1,2-diphenyl-1,2-di-p-tolylhydrazine 

Relevant articles and documents

Aerobic Oxidative Homo- and Cross-Coupling of Amines Catalyzed by Phenazine Radical Cations

Phenazine radical cations (PhRCs) were used for the first time as efficient metal-free catalysts for the oxidative homo- and cross-coupling of a variety of different amines. A series of functional PhRCs were prepared, characterized with X-ray diffraction, and their radical character was investigated with DFT calculations. They were tested as catalysts under neat conditions with low oxygen pressure to prepare homo- and cross-coupled aliphatic and aromatic imines in high yields. Although all synthesized phenazines were catalytically active, the highest reaction rates and the best selectivity were achieved using the 5,10-dihydro-5,10-dimethylphenazine radical cation. By means of fluorescence, UV-vis and EPR spectroscopy, a mechanism of the oxidative amine coupling, catalyzed by PhRCs, is proposed.