129866-69-9

Basic information

• Product Name: (E)-3-phenyl-2-propeneselenoic acid Se-phenyl ester
• Synonyms: (E)-3-phenyl-2-propeneselenoic acid Se-phenyl ester
• CAS NO: 129866-69-9
• Molecular Weight: 287.22
• Mol File: 129866-69-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (E)-3-phenyl-2-propeneselenoic acid Se-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-phenyl-2-propeneselenoic acid Se-phenyl ester(129866-69-9)
• EPA Substance Registry System: (E)-3-phenyl-2-propeneselenoic acid Se-phenyl ester(129866-69-9)

Safety Data

• Hazardous Substances Data: 129866-69-9(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 328012-09-5 (E)-1-(1H-benzo[d][1,2,3]triazol-1-yl)-3-phenylprop-2-en-1-one 
• 92593-15-2 selenophenyl α-methylcinnamate 
• 645-96-5 Benzeneselenol 
• 41924-21-4 phenyl tributylstannyl selenide 
• 102-92-1 Cinnamoyl chloride 
• 201230-82-2 carbon monoxide 
• 536-74-3 phenylacetylene 
• 34837-55-3 Phenylselenyl bromide 
• 140-10-3 (E)-3-phenylacrylic acid 
• 290820-91-6 bis(phenylselenato)zinc N,N,N',N'-tetramethylethylenediamine 
• 109-99-9 tetrahydrofuran 

Downstream Products

• 92593-16-3 selenophenyl α-phenylcinnamate 
• 92593-15-2 selenophenyl α-methylcinnamate 
• 62510-08-1 (E)-1,5-diphenyl-1-penten-3-one 
• 4764-21-0 2H-selenochromen-2-one 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

A stereoselective synthetic route to (E)-α,β-unsaturated selenoesters

Terminal alkynes 1 react with Cp2Zr(H)Cl (Cp = η5-C5H5) and CO to give acylzirconocene chloride derivatives 2, which are trapped with diaryldiselenides to afford (E)-α,β-unsaturated selenoesters.

Atom efficient preparation of zinc selenates for the synthesis of selenol esters under “On Water” conditions

We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)2Zn] or [(PhSe)2Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.

Investigation on the se-acylation with N-acylbenzotriazoles

The acylation of Se-nucleophiles with N-acylbenzotriazoles was investigated. Samarium phenylselenolate and benzylselenolate (RSeSmI 2) reacted with N-aroyl and N-alkanoylbenzotriazoles smoothly and afforded the corresponding selenol esters in g