13004-07-4

Basic information

• Product Name: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-, 4-methylbenzenesulfonate, trans-
• CAS NO: 13004-07-4
• Molecular Formula: C18H28O3S
• Molecular Weight: 324.485
• Mol File: 13004-07-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-, 4-methylbenzenesulfonate, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-, 4-methylbenzenesulfonate, trans-(13004-07-4)
• EPA Substance Registry System: Cyclohexanemethanol, 4-(1,1-dimethylethyl)-, 4-methylbenzenesulfonate, trans-(13004-07-4)

Safety Data

• Hazardous Substances Data: 13004-07-4(Hazardous Substances Data)

Upstream product

• 943-28-2 cis-4-t-butylcyclohexanecarboxylic acid 
• 13004-06-3 cis-(4-tert-butylcyclohexyl)methanol 
• 98-59-9 p-toluenesulfonyl chloride 
• 943-29-3 trans-4-(tert-butyl)cyclohexane-1-carboxylic acid 
• 10601-39-5 trans-(4-tert-butyl-cyclohexyl)-methanol 

Downstream Products

• 31499-51-1 cis-8-tert-butyl-1-oxaspiro[4.5]decan-2-one 
• 31610-67-0 trans-8-(tert-butyl)-1-oxaspiro[4.5]decan-2-one 
• 63724-09-4 4-(t-butyl)vinylcyclohexane 
• 1380424-73-6 C₁₄H₂₆ 
• 1380424-74-7 3-[(1s,4s)-4-(tert-butyl)cyclohexyl]propanoic acid 
• 37982-11-9 cis-4-tert-Butylcyclohexylcarbinylamin 
• 37982-12-0 trans-4-tert-Butylcyclohexylcarbinylamin 

Relevant articles and documents

Directed metal (oxo) aliphatic C-H hydroxylations: Overriding substrate bias

The first general strategy for a directing effect on metal (oxo)-promoted C-H hydroxylations is described. Carboxylic acid moieties on the substrate overcome unfavorable electronic, steric, and stereoelectronic biases in C-H hydroxylations catalyzed by the non-heme iron complex Fe(PDP). In a demonstration of the power of this directing effect, C-H oxidation is diverted away from an electronically favored C-1 H abstraction/rearrangement pathway in the paclitaxel framework to enable installation of C-2 oxidation in the naturally occurring oxidation state and stereoconfiguration.