130256-36-9

Basic information

• Product Name: (1S,3S,5R)-1-acetoxy-5-benzyloxy-3-cyclohexanol
• CAS NO: 130256-36-9
• Molecular Weight: 264.321
• Mol File: 130256-36-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,3S,5R)-1-acetoxy-5-benzyloxy-3-cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,3S,5R)-1-acetoxy-5-benzyloxy-3-cyclohexanol(130256-36-9)
• EPA Substance Registry System: (1S,3S,5R)-1-acetoxy-5-benzyloxy-3-cyclohexanol(130256-36-9)

Safety Data

• Hazardous Substances Data: 130256-36-9(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 130323-27-2 (1S,5R,7R)-3-Hydroxymethyl-2,4-dioxa-bicyclo[3.3.1]nonan-7-ol 
• 131245-85-7 (1S,3R,5S)-5-Benzyloxy-cyclohexane-1,3-diol 
• 50409-12-6 cis,cis-1,3,5-trihydroxycyclohexane 
• 130256-34-7 meso-1,3-cis,3,5-cis-1,3-diacetoxy-5-benzyloxycyclohexane 
• 95205-55-3 (1S,5R,7R)-3-Benzyloxymethyl-2,4-dioxa-bicyclo[3.3.1]nonan-7-ol 
• 50409-13-7 2,5,11-trioxatricyclo[4.3.1.14,8 ] undecan-3-one 
• 130256-33-6 (1R,5S,7R)-7-Benzyloxy-3-benzyloxymethyl-2,4-dioxa-bicyclo[3.3.1]nonane 

Downstream Products

• 130256-46-1 cis-5-(benzyloxy)-3-cyclohexen-1-ol 
• 140363-99-1 (2R,4R)-dimethyl 2-acetoxy-4-benzyloxyhexanedioate 
• 140364-00-7 (2R,4R)-dimethyl 4-benzyloxy-2-hydroxyhexanedioate 
• 140363-95-7 (3R,5S)-3-benzoyloxy-5-benzyloxy-1-cyclohexene 
• 140363-95-7 (3S,5S)-3-benzoyloxy-5-benzyloxy-1-cyclohexene 
• 140460-29-3 (4R,6R)-4-benzyloxy-6-methoxycarbonyltetrahydro-2-pyranone 
• 140460-25-9 cis-1,3-dibenzyloxycyclohexane 
• 131245-95-9 (3R,5S)-3-acetoxy-5-benzyloxy-1-cyclohexene 
• 140363-97-9 (1R,2S,3R,5R)-1,2,3-triacetoxy-5-benzyloxycyclohexane 
• 140363-98-0 (1R,2S,3R,5R)-1,2,3-triacetoxycyclohexan-5-ol 
• 140363-96-8 (+)-(1S,2R,4R,6R)-4-Benzyloxy-1,6-epoxycyclohexan-2-ol 
• 130256-46-1 (3S,5S)-5-benzyloxy-1-cyclohexen-3-ol 
• 130256-34-7 (1R,3R,5R)-1,3-diacetoxy-5-benzyloxycyclohexane 
• 137767-18-1 (3R,5S)-5-benzyloxy-1-cyclohexen-3-ol 

Relevant articles and documents

Enantioselective synthesis of (1S,3S,5R)-1-acetoxy-5-benzyl-oxycyclohexan-3-ol and its application to the synthesis of compactin lactone moiety and quinic acid

Porcine liver esterase (PLE)-catalyzed asymmetric hydrolysis of meso-1,3-cis,3,5-cis-1,3-diacetoxy-5-benzyloxycyclohexane 1 afforded (1S,3S,5R)-2 of 87% e.e. Starting from this compound, compactin lactone moiety 17A and its C-6 diastereomer 17B were diast

ENANTIOTOPOSELECTIVE PLE-CATALYZED HYDROLYSIS OF CIS-5-SUBSTITUTED-1,3-DIACYLOXYCYCLOHEXANES. PREPARATION OF SOME USEFUL CHIRAL BUILDING BLOCKS

PLE-catalyzed hydrolysis of prochiral cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane and cis-5-benzyloxy-1,3-diacetoxycyclohexane proceeds with high enantiotoposelectivity.The preparation of some useful chiral building blocks is described.