130256-34-7Relevant articles and documents
Enantioselective synthesis of (1S,3S,5R)-1-acetoxy-5-benzyl-oxycyclohexan-3-ol and its application to the synthesis of compactin lactone moiety and quinic acid
Suemune,Matsuno,Uchida,Sakai
, p. 297 - 306 (2007/10/02)
Porcine liver esterase (PLE)-catalyzed asymmetric hydrolysis of meso-1,3-cis,3,5-cis-1,3-diacetoxy-5-benzyloxycyclohexane 1 afforded (1S,3S,5R)-2 of 87% e.e. Starting from this compound, compactin lactone moiety 17A and its C-6 diastereomer 17B were diast
ENANTIOTOPOSELECTIVE PLE-CATALYZED HYDROLYSIS OF CIS-5-SUBSTITUTED-1,3-DIACYLOXYCYCLOHEXANES. PREPARATION OF SOME USEFUL CHIRAL BUILDING BLOCKS
Carda, M.,Eycken, J. Van der,Vandewalle, M.
, p. 17 - 20 (2007/10/02)
PLE-catalyzed hydrolysis of prochiral cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane and cis-5-benzyloxy-1,3-diacetoxycyclohexane proceeds with high enantiotoposelectivity.The preparation of some useful chiral building blocks is described.