1309576-54-2

Basic information

• Product Name: (1E,2E)-3-{1-[(p-trifluoromethylphenyl)imino]-2-(trimethylsilyl)-3-phenyl-2-propenyl}-4,4-dimethyl-1,3-oxazolidine-2-one
• CAS NO: 1309576-54-2
• Molecular Weight: 460.571
• Mol File: 1309576-54-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1E,2E)-3-{1-[(p-trifluoromethylphenyl)imino]-2-(trimethylsilyl)-3-phenyl-2-propenyl}-4,4-dimethyl-1,3-oxazolidine-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1E,2E)-3-{1-[(p-trifluoromethylphenyl)imino]-2-(trimethylsilyl)-3-phenyl-2-propenyl}-4,4-dimethyl-1,3-oxazolidine-2-one(1309576-54-2)
• EPA Substance Registry System: (1E,2E)-3-{1-[(p-trifluoromethylphenyl)imino]-2-(trimethylsilyl)-3-phenyl-2-propenyl}-4,4-dimethyl-1,3-oxazolidine-2-one(1309576-54-2)

Safety Data

• Hazardous Substances Data: 1309576-54-2(Hazardous Substances Data)

Upstream product

• 351-98-4 N-benzylidene-4-(trifluoromethyl)aniline 

Relevant articles and documents

Catalyst-controlled torquoselectivity switch in the 4π ring-opening reaction of 2-amino-2-azetines giving β-substituted α,β- unsaturated amidines

The torquoselectivity of the 4π electrocyclic ring-opening reaction of 2-azetines can be controlled by the Bronsted acidity of the catalyst and the polarity of the solvent. DFT calculations provided insight into the mechanism of this remarkable switch. Anti and syn stereoisomers of α,β-unsaturated amidines were selectively synthesized from ynamides and aldimines in the presence of Tf2NH and CSA, respectively.