132636-65-8Relevant articles and documents
Electronic effects on C-O-C ether bonds in 3-aryloxy derivatives of benzisothiazole 1,1-dioxides: rapid ethanolysis of 3-(4-nitrophenoxy)-1,2-benzisothiazole 1,1-dioxide, (1), to give 3-ethoxy-1,2-benzisothiazole 1,1-dioxide, (2)
Brigas,Goncalves,Johnstone
, p. 251 - 253 (1998)
The bond lengths in the central C-O-C ether link-age of title compound (1), C13H8N2O5S, are comparable with those found in earlier work on similar compounds. However, (1) was found to undergo very easy solvolysi
Metal-assisted reactions. Part 20. Catalytic transfer hydrogenolysis of phenolic C-O bonds
Brigas,Johnstone
, p. 5789 - 5790 (2007/10/02)
After conversion of phenols into O-pseudosaccharyl ethers (2) catalytic transfer hydrogenolysis with Pd/C catalyst and sodium phosphinate as hydrogen donor gave arenes (ArH) in good yield. As an example of the application of this reaction in synthesis, oestrone was onverted into oestratrienone in a high yielding, one step reaction.