13274-84-5

Basic information

• Product Name: ethenyl bis(chloromethyl)phosphinate
• Synonyms: ETHENYL BIS(CHLOROMETHYL) PHOSPHINATE
• CAS NO: 13274-84-5
• Molecular Formula: C₄H₉Cl₂O₂P
• Molecular Weight: 188.9769
• Mol File: 13274-84-5.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 210.1°C at 760 mmHg
• Flash Point: 57.8°C
• Density: 1.322g/cm³
• Vapor Pressure: 0.283mmHg at 25°C
• Refractive Index: 1.452
• CAS DataBase Reference: ethenyl bis(chloromethyl)phosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: ethenyl bis(chloromethyl)phosphinate(13274-84-5)
• EPA Substance Registry System: ethenyl bis(chloromethyl)phosphinate(13274-84-5)

Safety Data

• Hazardous Substances Data: 13274-84-5(Hazardous Substances Data)

Upstream product

• 21646-99-1 diphosphorous acid tetraethyl ester 
• 1825-62-3 ethyl trimethylsilyl ether 
• 13482-64-9 bis(chloromethyl)phosphinic chloride 
• 64-17-5 ethanol 
• 186667-83-4 C₃H₇Cl₄NO₂P₂ 
• 27445-88-1 tetrakis(chloromethyl)pyrophosphinate 

Downstream Products

• 17052-17-4 Bis-iodmethyl-phosphonsaeureethylester 
• 17052-15-2 Chlormethyl-iodmethyl-phosphonsaeure-ethylester 
• 18788-52-8 Bis-(O-n-butylphenylphosphinylmethyl)-phosphinsaeureethylester 
• 18788-51-7 bis ((diphenylphosphinyl)methyl) phosphinic acid 
• 21851-92-3 C₂₀H₂₉O₆P₃ 
• 21851-91-2 bis[(diphenylphosphinyl)methyl]ethyl phosphinate 

Relevant articles and documents

Mild synthesis of organophosphorus compounds: Reaction of phosphorus-containing carbenoids with organoboranes

Organoboranes react with phosphorus-containing carbenoids to produce a variety of functionalized organophosphorus compounds under mild conditions. In some cases, selective migration of one group atached to boron can be observed. Phosphonite-borane complexes are introduced as novel synthons for the synthesis of phosphinic esters.

Reaction of (chloromethyl)phosphonic(-phosphinic) chlorides with silylated protic nucleophiles

Reactions of (chloromethyl)phosphonic(-hosphinic) chlorides with trimethylalkoxy(-phenoxy, -dialkylamino)silanes are accompanied by elimination of trimethylchlorosilane and lead to formation of related substitution products. Reactions of bis(chloromethyl)phosphinic chloride and (chloromethyl)phosphinic dichloride with neutral and hydrogen silyl phosphites were studied. The reactions of bis(chloromethyl)phosphinic chloride with tris(trimethylsilyl)phosphite, diethyl trimethylsilyl phosphite, and bis(trimethylsilyl) hydrogen phosphite yield trimethylsilyl bis(chloromethyl)phosphinate. Similar reactions with (chloromethyl)phosphonic dichloride resulted in isolation of bis(trimethylsilyl) (chloromethyl)phosphonate.