1373444-00-8

Basic information

• Product Name: 2-(3-butynyl)-1-{[2-(3-butynyl)-6-methoxyphenyl]ethynyl}naphthalene
• Synonyms: 2-(3-butynyl)-1-{[2-(3-butynyl)-6-methoxyphenyl]ethynyl}naphthalene
• CAS NO: 1373444-00-8
• Molecular Weight: 362.471
• Mol File: 1373444-00-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(3-butynyl)-1-{[2-(3-butynyl)-6-methoxyphenyl]ethynyl}naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-butynyl)-1-{[2-(3-butynyl)-6-methoxyphenyl]ethynyl}naphthalene(1373444-00-8)
• EPA Substance Registry System: 2-(3-butynyl)-1-{[2-(3-butynyl)-6-methoxyphenyl]ethynyl}naphthalene(1373444-00-8)

Safety Data

• Hazardous Substances Data: 1373444-00-8(Hazardous Substances Data)

Upstream product

• 912469-48-8 [3-methoxy-2-(2-trimethylsilylethynyl)phenyl]methanol 
• 137898-13-6 2-trifluoromethylsulphonyloxy-3-methoxybenzaldehyde 

Relevant articles and documents

Nickel-Catalyzed Construction of Chiral 1-[6]Helicenols and Application in the Synthesis of [6]Helicene-Based Phosphinite Ligands

Two 1-[6]helicenol derivatives were synthesized by Ni-catalyzed [2+2+2] cycloaddition on a multigram scale. Both enantiomers of the 1-[6]helicenols could be efficiently prepared by simple optical resolution. As a synthetic application of helically chiral 1-[6]helicenols, a novel class of [6]helicene-based phosphinites was developed; these compounds represent the first examples of helically chiral phosphinite ligands. Up to 90 % ee was obtained for the Pd-catalyzed asymmetric allylic alkylation reaction.