137451-96-8

Basic information

• Product Name: C₂₄H₂₀
• Synonyms: C₂₄H₂₀
• CAS NO: 137451-96-8
• Molecular Weight: 308.423
• Mol File: 137451-96-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₂₄H₂₀(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₄H₂₀(137451-96-8)
• EPA Substance Registry System: C₂₄H₂₀(137451-96-8)

Safety Data

• Hazardous Substances Data: 137451-96-8(Hazardous Substances Data)

Upstream product

• 17343-74-7 1,1-dibromo-2,2-diphenylcyclopropane 
• 98-83-9 isopropenylbenzene 

Downstream Products

• 1333475-12-9 C₂₃H₂₅NO₃ 
• 1333475-17-4 C₂₂H₂₇NO 
• 1333475-19-6 C₁₈H₁₉NO₂ 
• 1333475-16-3 C₂₀H₂₃NO 
• 20595-82-8 α.N.N-Trimethyl-β.β-diphenyl-acrylamid 
• 1333475-13-0 C₂₈H₂₉NO 
• 1333475-15-2 C₁₉H₁₆N₂O 
• 1333475-06-1 C₂₀H₂₁NO₂ 
• 98-86-2 acetophenone 
• 1333475-11-8 C₂₁H₂₃NO 

Relevant articles and documents

Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with secondary amines under an oxygen atmosphere

A Midas touch! Gold(I)-catalyzed tandem oxidative ring-opening/C-C bond cleavage reactions of vinylidenecyclopropanes with a variety of secondary amines proceeded smoothly in toluene or 1,1,2,2-tetrachloroethane (TCE) to give the corresponding amides in moderate to good yields under oxygen atmosphere (see scheme; DCE=1,2-dichloroethane). The scope and limitations as well as the plausible mechanisms have been discussed.

General and Convenient Route to Alkenylidenecyclopropanes: Generation of Alkenylidenecarbenes from 1,1-Dibromocyclopropanes under Phase-transfer Conditions

Alkenylidenecyclopropanes have been prepared in a stereospecific manner by the reaction of 1,1-disubstituted 2,2-dibromocyclopropanes with sodium hydroxide under phase-transfer conditions in the presence of alkenes.