17343-74-7Relevant articles and documents
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Skell,Garner
, p. 5430 (1956)
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Photoredox-Catalyzed α-Aminoalkylcarboxylation of Allenes with CO2
Hahm, Hyungwoo,Baek, Doohyun,Kim, Dowon,Park, Seongwook,Ryoo, Jeong Yup,Hong, Sukwon
supporting information, p. 3879 - 3884 (2021/05/29)
The photoredox-catalyzed α-aminoalkylcarboxylation of aryl allenes with CO2 and N,N-dimethylanilines is reported for the first time (26 examples, up to 96% yield). In the case of electron-deficient allenes, good regioselectivity was observed (up to 94:6), exclusively generating kinetic products over thermodynamic products. This protocol is a novel synthetic method for highly functionalized β,γ-unsaturated γ-aminobutyric esters.
Synthesis of Polycyclic Aromatic Hydrocarbons Decorated by Fluorinated Carbon Acids/Carbanions
Hoshikawa, Shoki,Yanai, Hikaru,Martín-Mejías, Irene,Lázaro-Milla, Carlos,Aragoncillo, Cristina,Almendros, Pedro,Matsumoto, Takashi
supporting information, p. 16112 - 16116 (2021/10/12)
The carboarylation reaction of biphenyl-alkynes was successfully triggered by electrophilic attack of 1,1-bis(triflyl)ethylene on the alkyne moiety to give polycyclic aromatic hydrocarbons (PAHs) decorated by superacidic carbon acid functionality. Neutralisation of thus obtained acids with NaHCO3 yielded the corresponding sodium salts, which showed improved solubility in both aqueous and organic solvents.
A Simple Synthesis of 3,3-Diphenylcyclopropene
Nizovtsev, Alexey V.
, p. 537 - 542 (2020/09/09)
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